Photophysical Studies of Metal to Ligand Charge Transfer Involving Quadruply Bonded Complexes of Molybdenum and Tungsten

Malcolm H. Chisholm; Samantha E. Brown-Xu; Thomas F. Spilker

doi:10.1021/ar500256f

Photophysical Studies of Metal to Ligand Charge Transfer Involving Quadruply Bonded Complexes of Molybdenum and Tungsten

Accounts of Chemical Research ◽

10.1021/ar500256f ◽

2015 ◽

Vol 48 (3) ◽

pp. 877-885 ◽

Cited By ~ 20

Author(s):

Malcolm H. Chisholm ◽

Samantha E. Brown-Xu ◽

Thomas F. Spilker

Keyword(s):

Charge Transfer ◽

Ligand Charge Transfer ◽

Photophysical Studies ◽

And Tungsten ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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Electron delocalization in the S1 and T1 metal-to-ligand charge transfer states of trans-substituted metal quadruply bonded complexes

Proceedings of the National Academy of Sciences ◽

10.1073/pnas.1103082108 ◽

2011 ◽

Vol 108 (20) ◽

pp. 8152-8156 ◽

Cited By ~ 44

Author(s):

B. G. Alberding ◽

M. H. Chisholm ◽

J. C. Gallucci ◽

Y. Ghosh ◽

T. L. Gustafson

Keyword(s):

Charge Transfer ◽

Electron Delocalization ◽

Ligand Charge Transfer ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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Synthesis and characterization of trans-M2(TiPB)2(O2C-CHCH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(TiPB)2L2, where TiPB = 2,4,6-triisopropylbenzoate and L = π-accepting carboxylate ligand

Dalton Transactions ◽

10.1039/c1dt10788g ◽

2011 ◽

Vol 40 (40) ◽

pp. 10658 ◽

Cited By ~ 14

Author(s):

Brian G. Alberding ◽

Malcolm H. Chisholm ◽

Benjamin J. Lear ◽

Vesal Naseri ◽

Carly R. Reed

Keyword(s):

Charge Transfer ◽

Carboxylate Ligand ◽

Synthesis And Characterization ◽

Ligand Charge Transfer ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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Metal to ligand charge-transfer photochemistry of metal-metal bonded complexes 9. Photochemistry of CpFe(CO)2Re(CO)3L (L=4,4′-Me2-bpy; pyridine-2-carbaldehyde N-isopropylimine)

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)86780-8 ◽

1990 ◽

Vol 178 (2) ◽

pp. 185-194 ◽

Cited By ~ 17

Author(s):

Peter C. Servaas ◽

Gerard J. Stor ◽

Derk J. Stufkens ◽

Ad Oskam

Keyword(s):

Charge Transfer ◽

Ligand Charge Transfer ◽

Metal Metal ◽

Bonded Complexes

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Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes 11. Halogen atom and electron transfer reactions of (CO)5MM′(CO)3(α-diimine) (M, M′Mn, Re) complexes

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)90385-2 ◽

1991 ◽

Vol 187 (2) ◽

pp. 133-140 ◽

Cited By ~ 15

Author(s):

T. van der Graaf ◽

A. van Rooy ◽

D.J. Stufkens ◽

A. Oskam

Keyword(s):

Electron Transfer ◽

Charge Transfer ◽

Halogen Atom ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Ligand Charge Transfer ◽

Metal Metal ◽

Bonded Complexes

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ChemInform Abstract: Metal to Ligand Charge-Transfer Photochemistry of Metal-Metal-Bonded Complexes. Part 6. Photochemistry of Ph3SnM(CO)3(α-diimine) (M: Mn, Re): Evidence for Different Primary Photoprocesses of the Mn and Re Complexes.

ChemInform ◽

10.1002/chin.198920092 ◽

1989 ◽

Vol 20 (20) ◽

Author(s):

R. R. ANDREA ◽

W. G. J. DE LANGE ◽

D. J. STUFKENS ◽

A. OSKAM

Keyword(s):

Charge Transfer ◽

Ligand Charge Transfer ◽

Metal Metal ◽

Bonded Complexes

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Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 7. Photochemistry of (CO)4CoM(CO)3(bpy) (M = Mn, Re; bpy = 2,2'-bipyridine): photocatalytic disproportionation of the manganese complex in the presence of PR3

Inorganic Chemistry ◽

10.1021/ic00300a017 ◽

1989 ◽

Vol 28 (1) ◽

pp. 75-81 ◽

Cited By ~ 28

Author(s):

Hans K. Van Dijk ◽

Jos Van der Haar ◽

Derk J. Stufkens ◽

Ad Oskam

Keyword(s):

Charge Transfer ◽

Manganese Complex ◽

Ligand Charge Transfer ◽

Metal Metal ◽

Bonded Complexes

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Photochemistry of metal-metal-bonded complexes. 2. MLCT(metal-ligand charge transfer) photochemistry of (CO)5MM'(CO)3(R-DAB) (M, M' = Mn, Re; DAB = 1,4-diaza-1,3-butadiene) in inert-gas matrixes at 10 K and in PVC film at 193 and 293 K

Inorganic Chemistry ◽

10.1021/ic00219a043 ◽

1985 ◽

Vol 24 (25) ◽

pp. 4411-4416 ◽

Cited By ~ 26

Author(s):

Maarten W. Kokkes ◽

Derk J. Stufkens ◽

Ad Oskam

Keyword(s):

Charge Transfer ◽

Inert Gas ◽

Ligand Charge Transfer ◽

Pvc Film ◽

Metal Metal ◽

Metal Ligand ◽

Bonded Complexes

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Metal to Ligand Charge-Transfer Photochemistry of Metal-Metal-Bonded Complexes. 12. The Primary Photoprocess of (CO)5ReMn(CO)3(.alpha.-diimine) Complexes Studied by Temperature- and Pressure-Dependent Photochemistry and Pico- and Nanosecond Flash Photolysis

Inorganic Chemistry ◽

10.1021/ic00091a030 ◽

1994 ◽

Vol 33 (13) ◽

pp. 2865-2873 ◽

Cited By ~ 17

Author(s):

Brenda D. Rossenaar ◽

Tim van der Graaf ◽

Rudi van Eldik ◽

Cooper H. Langford ◽

Derk J. Stufkens ◽

...

Keyword(s):

Charge Transfer ◽

Flash Photolysis ◽

Ligand Charge Transfer ◽

Metal Metal ◽

Temperature And Pressure ◽

Diimine Complexes ◽

Bonded Complexes

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Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 6. Photochemistry of Ph3SnM(CO)3(.alpha.-diimine) (M = Mn, Re): evidence for different primary photoprocesses of the manganese and rhenium complexes

Inorganic Chemistry ◽

10.1021/ic00301a033 ◽

1989 ◽

Vol 28 (2) ◽

pp. 318-323 ◽

Cited By ~ 26

Author(s):

Ronald R. Andrea ◽

Wim G. J. De Lange ◽

Derk J. Stufkens ◽

Ad Oskam

Keyword(s):

Charge Transfer ◽

Rhenium Complexes ◽

Ligand Charge Transfer ◽

Metal Metal ◽

Bonded Complexes

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Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 8. Photochemistry of (pentacarbonylmanganese)tricarbonyl(.alpha.-diimine)manganese complexes. Coupling reactions of the radicals formed and x-ray structure of the photoproduct (CO)4Mn(.sigma.-N,.sigma.-N',.eta.2-CN-iso-Pr-PyCa)Mn(CO)3 (iso-Pr-PyCa = pyridine-2-carbaldehyde-N-isopropylimine).

Inorganic Chemistry ◽

10.1021/ic00004a004 ◽

1991 ◽

Vol 30 (4) ◽

pp. 599-608 ◽

Cited By ~ 31

Author(s):

Tim. Van der Graaf ◽

Derk J. Stufkens ◽

Ad. Oskam ◽

Kees. Goubitz

Keyword(s):

Charge Transfer ◽

Manganese Complexes ◽

Coupling Reactions ◽

X Ray ◽

Ligand Charge Transfer ◽

Metal Metal ◽

Bonded Complexes

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