Infrared Spectroscopy Investigation of the Acid Sites in the Metal–Organic Framework Aluminum Trimesate MIL-100(Al)

2012 ◽  
Vol 116 (9) ◽  
pp. 5710-5719 ◽  
Author(s):  
Christophe Volkringer ◽  
Hervé Leclerc ◽  
Jean-Claude Lavalley ◽  
Thierry Loiseau ◽  
Gérard Férey ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Metal–Organic Framework-Based Solid Acid Materials for Biomass Upgrade

2021 ◽  
Author(s):  
Yutian Qin ◽  
Jun Guo ◽  
Meiting Zhao
Keyword(s):  
High Efficiency ◽  
Solid Acid ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Solid Acid Catalysts ◽  
Future Research ◽  
Acid Catalysts ◽  
Metal Organic ◽  
Biomass Transformation ◽  
Organic Framework

AbstractBiomass is a green and producible source of energy and chemicals. Hence, developing high-efficiency catalysts for biomass utilization and transformation is urgently demanded. Metal–organic framework (MOF)-based solid acid materials have been considered as promising catalysts in biomass transformation. In this review, we first introduce the genre of Lewis acid and Brønsted acid sites commonly generated in MOFs or MOF-based composites. Then, the methods for the generation and adjustment of corresponding acid sites are overviewed. Next, the catalytic applications of MOF-based solid acid materials in various biomass transformation reactions are summarized and discussed. Furthermore, based on our personal insights, the challenges and outlook on the future development of MOF-based solid acid catalysts are provided. We hope that this review will provide an instructive roadmap for future research on MOFs and MOF-based composites for biomass transformation.

A zwitterionic metal–organic framework with free carboxylic acid sites that exhibits enhanced hydrogen adsorption energies

CrystEngComm ◽  
2013 ◽  
Vol 15 (45) ◽  
pp. 9408 ◽  
Author(s):  
Marianne B. Lalonde ◽  
Rachel B. Getman ◽  
Jeong Yong Lee ◽  
John M. Roberts ◽  
Amy A. Sarjeant ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Metal Organic ◽  
Adsorption Energies ◽  
Organic Framework

A multifunctional photochromic metal–organic framework with Lewis acid sites for selective amine and anion sensing

CrystEngComm ◽  
2020 ◽  
Vol 22 (24) ◽  
pp. 4124-4129 ◽  
Author(s):  
Jian-Jun Liu ◽  
Qi-Tao Que ◽  
Dan Liu ◽  
Hongbo Suo ◽  
Jiaming Liu ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Colorimetric Sensor ◽  
Selective Detection ◽  
Lewis Acid Sites ◽  
Photochromic Properties ◽  
Anion Sensing ◽  
Metal Organic ◽  
Organic Framework

A bipyridinium-based MOF was prepared, which exhibits reversible photochromic properties, good luminescence sensing ability for Cr2O72−, and can be considered an excellent colorimetric sensor for the selective detection of amine vapors.

Highly Selective Quantum Sieving of D2 from H2 by a Metal–Organic Framework As Determined by Gas Manometry and Infrared Spectroscopy

2013 ◽  
Vol 135 (25) ◽  
pp. 9458-9464 ◽  
Author(s):  
Stephen A. FitzGerald ◽  
Christopher J. Pierce ◽  
Jesse L. C. Rowsell ◽  
Eric D. Bloch ◽  
Jarad A. Mason
Keyword(s):  
Infrared Spectroscopy ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Correction: A multifunctional photochromic metal–organic framework with Lewis acid sites for selective amine and anion sensing

CrystEngComm ◽  
2022 ◽  
Author(s):  
Jian-Jun Liu ◽  
Qi-Tao Que ◽  
Dan Liu ◽  
Hongbo Suo ◽  
Jiaming Liu ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Lewis Acid Sites ◽  
Anion Sensing ◽  
Metal Organic ◽  
Organic Framework

Correction for ‘A multifunctional photochromic metal–organic framework with Lewis acid sites for selective amine and anion sensing’ by Jian-Jun Liu et al., CrystEngComm, 2020, 22, 4124–4129, DOI: 10.1039/D0CE00560F.

scholarly journals Nanoweb Surface‐Mounted Metal–Organic Framework Films with Tunable Amounts of Acid Sites as Tailored Catalysts

2019 ◽  
Vol 26 (3) ◽  
pp. 691-698 ◽  
Author(s):  
Laurens D. B. Mandemaker ◽  
Miguel Rivera‐Torrente ◽  
Guusje Delen ◽  
Jan P. Hofmann ◽  
Matthias Lorenz ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Acid Sites ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Structural, elastic, thermal, and electronic responses of small-molecule-loaded metal–organic framework materials

2015 ◽  
Vol 3 (3) ◽  
pp. 986-995 ◽  
Author(s):  
Pieremanuele Canepa ◽  
Kui Tan ◽  
Yingjie Du ◽  
Hongbing Lu ◽  
Yves J. Chabal ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Ab Initio ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
Nano Indentation ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

We combine infrared spectroscopy, nano-indentation measurements, and ab initio simulations to study the evolution of structural, elastic, thermal, and electronic responses of the metal–organic framework MOF-74-Zn when loaded with H2, CO2, CH4, and H2O.

Sign in / Sign up

Export Citation Format

Share Document