A Metal−Organic Framework Functionalized with Free Carboxylic Acid Sites and Its Selective Binding of a Cl(H2O)4-Cluster

2005 ◽  
Vol 127 (47) ◽  
pp. 16362-16363 ◽  
Author(s):  
Radu Custelcean ◽  
Maryna G. Gorbunova
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Selective Binding ◽  
Metal Organic ◽  
Organic Framework

A zwitterionic metal–organic framework with free carboxylic acid sites that exhibits enhanced hydrogen adsorption energies

CrystEngComm ◽  
2013 ◽  
Vol 15 (45) ◽  
pp. 9408 ◽  
Author(s):  
Marianne B. Lalonde ◽  
Rachel B. Getman ◽  
Jeong Yong Lee ◽  
John M. Roberts ◽  
Amy A. Sarjeant ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Metal Organic ◽  
Adsorption Energies ◽  
Organic Framework

scholarly journals Metal–Organic Framework-Based Solid Acid Materials for Biomass Upgrade

2021 ◽  
Author(s):  
Yutian Qin ◽  
Jun Guo ◽  
Meiting Zhao
Keyword(s):  
High Efficiency ◽  
Solid Acid ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Solid Acid Catalysts ◽  
Future Research ◽  
Acid Catalysts ◽  
Metal Organic ◽  
Biomass Transformation ◽  
Organic Framework

AbstractBiomass is a green and producible source of energy and chemicals. Hence, developing high-efficiency catalysts for biomass utilization and transformation is urgently demanded. Metal–organic framework (MOF)-based solid acid materials have been considered as promising catalysts in biomass transformation. In this review, we first introduce the genre of Lewis acid and Brønsted acid sites commonly generated in MOFs or MOF-based composites. Then, the methods for the generation and adjustment of corresponding acid sites are overviewed. Next, the catalytic applications of MOF-based solid acid materials in various biomass transformation reactions are summarized and discussed. Furthermore, based on our personal insights, the challenges and outlook on the future development of MOF-based solid acid catalysts are provided. We hope that this review will provide an instructive roadmap for future research on MOFs and MOF-based composites for biomass transformation.

High-Throughput Aided Synthesis of the Porous Metal−Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization

2010 ◽  
Vol 49 (21) ◽  
pp. 9852-9862 ◽  
Author(s):  
Christophe Volkringer ◽  
Thierry Loiseau ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Mohamed Haouas ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
High Throughput ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

A zinc(ii) metal–organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid

CrystEngComm ◽  
2019 ◽  
Vol 21 (24) ◽  
pp. 3679-3685 ◽  
Author(s):  
Donghai Sheng ◽  
Ying Zhang ◽  
Yang Han ◽  
Guang Xu ◽  
Qingxiang Song ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Uptake Capacity ◽  
High Affinity ◽  
Metal Organic ◽  
Organic Framework

A new metal–organic framework {[Zn2(Htzba)2(dmtrz)]·(CH3)2NH}n (1) has already been solvothermally synthesized that exhibits a high CO2 uptake capacity.

Functionalized Defects through Solvent-Assisted Linker Exchange: Synthesis, Characterization, and Partial Postsynthesis Elaboration of a Metal–Organic Framework Containing Free Carboxylic Acid Moieties

2015 ◽  
Vol 54 (4) ◽  
pp. 1785-1790 ◽  
Author(s):  
Olga Karagiaridi ◽  
Nicolaas A. Vermeulen ◽  
Rachel C. Klet ◽  
Timothy C. Wang ◽  
Peyman Z. Moghadam ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

scholarly journals Selective Binding of O2over N2in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites

2011 ◽  
Vol 133 (37) ◽  
pp. 14814-14822 ◽  
Author(s):  
Eric D. Bloch ◽  
Leslie J. Murray ◽  
Wendy L. Queen ◽  
Sachin Chavan ◽  
Sergey N. Maximoff ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Binding ◽  
Coordination Sites ◽  
Redox Active ◽  
Active Metal ◽  
Metal Organic ◽  
Redox Active Metal ◽  
Organic Framework

A proton-conducting lanthanide metal–organic framework integrated with a dielectric anomaly and second-order nonlinear optical effect

2014 ◽  
Vol 50 (49) ◽  
pp. 6513-6516 ◽  
Author(s):  
Xiaoqiang Liang ◽  
Feng Zhang ◽  
Haixia Zhao ◽  
Wei Ye ◽  
Lasheng Long ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Nonlinear Optical ◽  
Metal Organic Framework ◽  
Dielectric Anomaly ◽  
Second Order ◽  
Optical Effect ◽  
Nonlinear Optical Effect ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework

A multifunctional metal–organic framework, {[Gd4(R-ttpc)2(R-Httpc)2(HCOO)2(H2O)8]·4H2O}n [JUC-125, R-H3ttpc = (3R,3′R,3′′R)-1,1′,1′′-(1,3,5-triazine-2,4,6-triyl)-tripiperidine-3-carboxylic acid], shows proton conduction, dielectric anomalous behaviour and a second-order NLO effect.

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