A Thermally Stable Pt/Y-Based Metal−Organic Framework:  Exploring the Accessibility of the Metal Centers with Spectroscopic Methods Using H2O, CH3OH, and CH3CN as Probes

2006 ◽  
Vol 110 (43) ◽  
pp. 21509-21520 ◽  
Author(s):  
Kai Chung Szeto ◽  
Karl Petter Lillerud ◽  
Mats Tilset ◽  
Morten Bjørgen ◽  
Carmelo Prestipino ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Spectroscopic Methods ◽  
Thermally Stable ◽  
Metal Centers ◽  
Metal Organic ◽  
Organic Framework

Synthesis, structure and properties of a high-energy metal−organic framework fuel [Cu(MTZ)2(CTB)2]n

2022 ◽  
Author(s):  
Hao-Zheng Mei ◽  
Yiqiang Xu ◽  
Guorong Lei ◽  
Wenli Cao ◽  
Zhimin Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Energy ◽  
Structure And Properties ◽  
Metal Centers ◽  
Metal Organic ◽  
Organic Framework

In this study, a novel high-energy metal-organic framework (MOF, [Cu(MTZ)2(CTB)2]n) was constructed based on the nitrogen-rich cyanotetrazolylborohydride (CTB) and 1-methyltriazole (MTZ) ligands, with Cu2+ as the autocatalytic metal centers. The...

Zn(ii)-based metal–organic framework: an exceptionally thermally stable, guest-free low dielectric material

2017 ◽  
Vol 5 (6) ◽  
pp. 1508-1513 ◽  
Author(s):  
Shruti Mendiratta ◽  
Muhammad Usman ◽  
Chun-Chi Chang ◽  
Yung-Chi Lee ◽  
Jenq-Wei Chen ◽  
...  
Keyword(s):  
Dielectric Material ◽  
Metal Organic Framework ◽  
Dielectric Behaviour ◽  
Thermally Stable ◽  
Low Dielectric ◽  
Metal Organic ◽  
Organic Framework

An exceptional thermally stable, chemically stable and guest-free Zn-based metal–organic framework exhibits low dielectric behaviour.

A Water and Thermally Stable Metal–Organic Framework Featuring Selective CO2 Adsorption

2013 ◽  
Vol 13 (9) ◽  
pp. 4125-4130 ◽  
Author(s):  
Yameng Li ◽  
Zhanfeng Ju ◽  
Benlai Wu ◽  
Daqiang Yuan
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Thermally Stable ◽  
Metal Organic ◽  
Organic Framework

A New Approach to Non-Coordinating Anions: Lewis Acid Enhancement of Porphyrin Metal Centers in a Zwitterionic Metal–Organic Framework

2016 ◽  
Vol 138 (32) ◽  
pp. 10293-10298 ◽  
Author(s):  
Jacob A. Johnson ◽  
Brenna M. Petersen ◽  
Attila Kormos ◽  
Elena Echeverría ◽  
Yu-Sheng Chen ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Metal Organic Framework ◽  
New Approach ◽  
Metal Centers ◽  
Metal Organic ◽  
Organic Framework

Linearly bridging CO2 in a metal–organic framework

2015 ◽  
Vol 51 (40) ◽  
pp. 8446-8449 ◽  
Author(s):  
Fei-Yan Yi ◽  
Hai-Long Jiang ◽  
Zhong-Ming Sun
Keyword(s):  
Single Crystal ◽  
Coordination Mode ◽  
Metal Organic Framework ◽  
Ambient Conditions ◽  
X Ray Diffraction ◽  
Metal Centers ◽  
X Ray ◽  
New Strategy ◽  
Metal Organic ◽  
Organic Framework

A very rare CO2-coordinated metal–organic framework was structurally confirmed by single-crystal X-ray diffraction. The CO2 ligand links two open Zn metal centers in an absolutely linear μ(O,O′) coordination mode with a CO distance of 1.107(4) Å. The new complex reported here is stable under ambient conditions and may provide a new strategy for CO2 fixation.

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