A New Approach to Non-Coordinating Anions: Lewis Acid Enhancement of Porphyrin Metal Centers in a Zwitterionic Metal–Organic Framework

2016 ◽  
Vol 138 (32) ◽  
pp. 10293-10298 ◽  
Author(s):  
Jacob A. Johnson ◽  
Brenna M. Petersen ◽  
Attila Kormos ◽  
Elena Echeverría ◽  
Yu-Sheng Chen ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Metal Organic Framework ◽  
New Approach ◽  
Metal Centers ◽  
Metal Organic ◽  
Organic Framework

Synthesis, structure and properties of a high-energy metal−organic framework fuel [Cu(MTZ)2(CTB)2]n

2022 ◽  
Author(s):  
Hao-Zheng Mei ◽  
Yiqiang Xu ◽  
Guorong Lei ◽  
Wenli Cao ◽  
Zhimin Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Energy ◽  
Structure And Properties ◽  
Metal Centers ◽  
Metal Organic ◽  
Organic Framework

In this study, a novel high-energy metal-organic framework (MOF, [Cu(MTZ)2(CTB)2]n) was constructed based on the nitrogen-rich cyanotetrazolylborohydride (CTB) and 1-methyltriazole (MTZ) ligands, with Cu2+ as the autocatalytic metal centers. The...

Highly effective Brønsted base/lewis acid cooperative catalysis: a new Cd metal–organic framework for the synthesis of Hantzsch 1,4-DHPs at ambient temperature

2017 ◽  
Vol 41 (24) ◽  
pp. 15475-15484 ◽  
Author(s):  
Farzaneh Rouhani ◽  
Ali Morsali
Keyword(s):  
Ambient Temperature ◽  
Lewis Acid ◽  
Functional Group ◽  
Metal Organic Framework ◽  
Cooperative Catalysis ◽  
Highly Effective ◽  
Metal Organic ◽  
Brønsted Base ◽  
Organic Framework

A new 3D metal–organic framework {[Cd3(BDC)3(OPP)(DMF)2]·2DMA}n (TMU-33) has been synthesized. The performance of the imine functional group of the OPP ligand as a Brønsted base and open Cd site as a Lewis acid in this framework was investigated as cooperative catalyst.

scholarly journals Tandem catalysis with a bifunctional site-isolated Lewis acid–Brønsted base metal–organic framework, NH2-MIL-101(Al)

2012 ◽  
Vol 48 (95) ◽  
pp. 11650 ◽  
Author(s):  
Renganathan Srirambalaji ◽  
Soonsang Hong ◽  
Ramalingam Natarajan ◽  
Minyoung Yoon ◽  
Raghunandan Hota ◽  
...  
Keyword(s):  
Base Metal ◽  
Lewis Acid ◽  
Metal Organic Framework ◽  
Tandem Catalysis ◽  
Metal Organic ◽  
Brønsted Base ◽  
Organic Framework
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