Hypervalent Iodine Chemistry:  Mechanistic Investigation of the Novel Haloacetoxylation, Halogenation, and Acetoxylation Reactions of 1,4-Dimethoxynaphthalenes

1997 ◽  
Vol 62 (16) ◽  
pp. 5321-5326 ◽  
Author(s):  
P. Andrew Evans ◽  
Thomas A. Brandt
Keyword(s):  
Hypervalent Iodine ◽  
The Novel ◽  
Mechanistic Investigation ◽  
Iodine Chemistry

The aryl iodine-catalyzed organic transformation via hypervalent iodine species generated in situ

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Xuemin Li ◽  
Guangchen Li ◽  
Yifu Cheng ◽  
Yunfei Du
Keyword(s):  
Organic Synthesis ◽  
Oxidative Coupling ◽  
Hypervalent Iodine ◽  
Organic Transformations ◽  
Aryl Iodide ◽  
Oxidative Reaction ◽  
Iodine Species ◽  
Iodine Chemistry

Abstract The application of hypervalent iodine species generated in situ in organic transformations has emerged as a useful and powerful tool in organic synthesis, allowing for the construction of a series of bond formats via oxidative coupling. Among these transformations, the catalytic aryl iodide can be oxidized to hypervalent iodine species, which then undergoes oxidative reaction with the substrates and the aryl iodine regenerated again once the first cyclic cycle of the reaction is completed. This review aims to systematically summarize and discuss the main progress in the application of in situ-generated hypervalent iodine species, providing references and highlights for synthetic chemists who might be interested in this field of hypervalent iodine chemistry.

Introduction of Hypervalent Iodine Chemistry and Its Application

Daxue Huaxue ◽  
2019 ◽  
Vol 34 (2) ◽  
pp. 1-16
Author(s):  
Dan LIU ◽  
◽  
Jiahao HE ◽  
Chi ZHANG
Keyword(s):  
Hypervalent Iodine ◽  
Iodine Chemistry

scholarly journals Mechanistic investigation into phenol oxidation by IBX elucidated by DFT calculations

2020 ◽  
Vol 18 (6) ◽  
pp. 1117-1129 ◽  
Author(s):  
Amritpal Kaur ◽  
Alireza Ariafard
Keyword(s):  
Density Functional Theory ◽  
Dft Calculations ◽  
Density Functional ◽  
Phenol Oxidation ◽  
Hypervalent Iodine ◽  
Functional Theory ◽  
Mechanistic Investigation ◽  
Oxidation Of Phenols ◽  
Double Oxidation

Density functional theory (DFT) at the SMD/M06-2X/def2-TZVP//SMD/M06-2X/LANL2DZ(d),6-31G(d) level was used to explore the regioselective double oxidation of phenols by a hypervalent iodine(v) reagent (IBX) to give o-quinones.

Hypervalent iodine chemistry—recent advances and applications

Tetrahedron ◽  
2010 ◽  
Vol 66 (31) ◽  
pp. 5737-5738 ◽  
Author(s):  
Stéphane Quideau ◽  
Thomas Wirth
Keyword(s):  
Hypervalent Iodine ◽  
Recent Advances ◽  
Iodine Chemistry

DFT Mechanistic Investigation into BF3-Catalyzed Alcohol Oxidation by a Hypervalent Iodine(III) Compound

ACS Catalysis ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 6510-6521 ◽  
Author(s):  
Kaveh Farshadfar ◽  
Antony Chipman ◽  
Brian F. Yates ◽  
Alireza Ariafard
Keyword(s):  
Alcohol Oxidation ◽  
Hypervalent Iodine ◽  
Mechanistic Investigation

Hypervalent iodine reactions utilized in carbon–carbon bond formations

2019 ◽  
Vol 17 (34) ◽  
pp. 7822-7848 ◽  
Author(s):  
I. F. Dempsey Hyatt ◽  
Loma Dave ◽  
Navindra David ◽  
Kirandeep Kaur ◽  
Marly Medard ◽  
...  
Keyword(s):  
Electrophilic Substitution ◽  
Hypervalent Iodine ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Recent Developments ◽  
Iodine Chemistry

This review covers recent developments of hypervalent iodine chemistry in dearomatizations, radicals, hypervalent iodine-guided electrophilic substitution, arylations, photoredox, and more.

A FACILE PREPARATION OF 3-HALOFLAVONES USING HYPERVALENT IODINE* CHEMISTRY

2001 ◽  
Vol 31 (14) ◽  
pp. 2101-2106 ◽  
Author(s):  
Ho Sik Rho ◽  
Byoung-Seob Ko ◽  
Young-Sung Ju
Keyword(s):  
Hypervalent Iodine ◽  
Facile Preparation ◽  
Iodine Chemistry
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