Hypervalent iodine reactions utilized in carbon–carbon bond formations

2019 ◽  
Vol 17 (34) ◽  
pp. 7822-7848 ◽  
Author(s):  
I. F. Dempsey Hyatt ◽  
Loma Dave ◽  
Navindra David ◽  
Kirandeep Kaur ◽  
Marly Medard ◽  
...  
Keyword(s):  
Electrophilic Substitution ◽  
Hypervalent Iodine ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Recent Developments ◽  
Iodine Chemistry

This review covers recent developments of hypervalent iodine chemistry in dearomatizations, radicals, hypervalent iodine-guided electrophilic substitution, arylations, photoredox, and more.

Carbon-Carbon Bond Formation Via Hypervalent Iodine Oxidations

Synthesis ◽  
1990 ◽  
Vol 1990 (06) ◽  
pp. 431-447 ◽  
Author(s):  
Robert M. Moriarty ◽  
Radhe K. Vaid
Keyword(s):  
Bond Formation ◽  
Hypervalent Iodine ◽  
Carbon Bond ◽  
Carbon Carbon Bond

scholarly journals Organic synthesis using (diacetoxyiodo)benzene (DIB): Unexpected and novel oxidation of 3-oxo-butanamides to 2,2-dihalo-N-phenylacetamides

2012 ◽  
Vol 8 ◽  
pp. 344-348 ◽  
Author(s):  
Wei-Bing Liu ◽  
Cui Chen ◽  
Qing Zhang ◽  
Zhi-Bo Zhu
Keyword(s):  
Chemical Synthesis ◽  
Organic Synthesis ◽  
Lewis Acid ◽  
Reliable Method ◽  
Hypervalent Iodine ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Direct Preparation

A novel and reliable method for the direct preparation of 2,2-dihalo-N-phenylacetamides is reported. The key transformation involves the cleavage of a carbon–carbon bond in the presence of DIB and a Lewis acid as the halogen source, and thus this method significantly expands the value of DIB as a unique and powerful tool in chemical synthesis. This protocol not only adds a new aspect to reactions that use other hypervalent iodine reagents but also provides a wide space for the synthesis of disubstituted acetamides.

Recent Developments in the Formation of Carbon—Carbon Bond Reactions Catalyzed by Metalloporphyrins

ChemInform ◽  
2004 ◽  
Vol 35 (21) ◽  
Author(s):  
Pietro Tagliatesta ◽  
Barbara Floris ◽  
Pierluca Galloni
Keyword(s):  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Recent Developments
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