ChemInform Abstract: Organic Hypervalent Iodine Chemistry Spanning Three Centuries - A Historical Overview

ChemInform ◽  
2010 ◽  
Vol 41 (45) ◽  
pp. no-no
Author(s):  
Anastasios Varvoglis
Keyword(s):  
Hypervalent Iodine ◽  
Historical Overview ◽  
Iodine Chemistry

The aryl iodine-catalyzed organic transformation via hypervalent iodine species generated in situ

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Xuemin Li ◽  
Guangchen Li ◽  
Yifu Cheng ◽  
Yunfei Du
Keyword(s):  
Organic Synthesis ◽  
Oxidative Coupling ◽  
Hypervalent Iodine ◽  
Organic Transformations ◽  
Aryl Iodide ◽  
Oxidative Reaction ◽  
Iodine Species ◽  
Iodine Chemistry

Abstract The application of hypervalent iodine species generated in situ in organic transformations has emerged as a useful and powerful tool in organic synthesis, allowing for the construction of a series of bond formats via oxidative coupling. Among these transformations, the catalytic aryl iodide can be oxidized to hypervalent iodine species, which then undergoes oxidative reaction with the substrates and the aryl iodine regenerated again once the first cyclic cycle of the reaction is completed. This review aims to systematically summarize and discuss the main progress in the application of in situ-generated hypervalent iodine species, providing references and highlights for synthetic chemists who might be interested in this field of hypervalent iodine chemistry.

Introduction of Hypervalent Iodine Chemistry and Its Application

Daxue Huaxue ◽  
2019 ◽  
Vol 34 (2) ◽  
pp. 1-16
Author(s):  
Dan LIU ◽  
◽  
Jiahao HE ◽  
Chi ZHANG
Keyword(s):  
Hypervalent Iodine ◽  
Iodine Chemistry

Hypervalent iodine chemistry—recent advances and applications

Tetrahedron ◽  
2010 ◽  
Vol 66 (31) ◽  
pp. 5737-5738 ◽  
Author(s):  
Stéphane Quideau ◽  
Thomas Wirth
Keyword(s):  
Hypervalent Iodine ◽  
Recent Advances ◽  
Iodine Chemistry

Hypervalent iodine reactions utilized in carbon–carbon bond formations

2019 ◽  
Vol 17 (34) ◽  
pp. 7822-7848 ◽  
Author(s):  
I. F. Dempsey Hyatt ◽  
Loma Dave ◽  
Navindra David ◽  
Kirandeep Kaur ◽  
Marly Medard ◽  
...  
Keyword(s):  
Electrophilic Substitution ◽  
Hypervalent Iodine ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Recent Developments ◽  
Iodine Chemistry

This review covers recent developments of hypervalent iodine chemistry in dearomatizations, radicals, hypervalent iodine-guided electrophilic substitution, arylations, photoredox, and more.

A FACILE PREPARATION OF 3-HALOFLAVONES USING HYPERVALENT IODINE* CHEMISTRY

2001 ◽  
Vol 31 (14) ◽  
pp. 2101-2106 ◽  
Author(s):  
Ho Sik Rho ◽  
Byoung-Seob Ko ◽  
Young-Sung Ju
Keyword(s):  
Hypervalent Iodine ◽  
Facile Preparation ◽  
Iodine Chemistry

scholarly journals Intramolecular Oxidative Diaryl Coupling of Tetrasubstituted Diphenylamines for Preparation of Bis(trifluoromethyl) Dimethyl Carbazoles

SynOpen ◽  
2021 ◽  
Author(s):  
Addison M Duda ◽  
Michael T Giurini ◽  
Jason G Gillmore ◽  
Thomas F Guarr
Keyword(s):  
Electron Transfer ◽  
Precious Metal ◽  
Metal Catalysts ◽  
Single Electron ◽  
Hypervalent Iodine ◽  
Single Electron Transfer ◽  
Primary Interest ◽  
Battery Materials ◽  
Precious Metal Catalysts ◽  
Iodine Chemistry

Synthetic preparation of carbazoles can be challenging, requiring ring building strategies and/or precious metal catalysts. Presented herein is a method for preparation of carbazoles with the use of inexpensive and reliable hypervalent iodine chemistry. An oxidative single electron transfer (SET) event initiates cyclization for preparation of our trifluoromethyl carbazoles. This method has been shown to be useful for a variety of bis(trifluoromethyl)carbazole isomers that are of primary interest for use as battery materials.

Sustainable Methods in Hypervalent Iodine Chemistry

2022 ◽  
pp. 335-386
Author(s):  
Brandon Frey † ◽  
Asim Maity † ◽  
Hao Tan ◽  
Pritam Roychowdhury ◽  
David C. Powers
Keyword(s):  
Hypervalent Iodine ◽  
Iodine Chemistry
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