Mechanism and linear free energy relationships in the kinetics of formation of bicyclo[3.3.1]nonane derivatives from 1,3,5-trinitrobenzene, benzoylacetones, and base

1985 ◽  
Vol 50 (8) ◽  
pp. 1178-1182 ◽  
Author(s):  
Lalitha Mary Gnanadoss ◽  
D. Kalaivani
2020 ◽  
Vol 18 (11) ◽  
pp. 2113-2119 ◽  
Author(s):  
Mads Mansø ◽  
Anne Ugleholdt Petersen ◽  
Kasper Moth-Poulsen ◽  
Mogens Brøndsted Nielsen

The kinetics of the thermal quadricyclane-to-norbornadiene (QC-to-NBD) isomerization follows a linear-free-energy relationship when using Creary radical values for a selection of aryl/cyano disubstituted derivatives.


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