ChemInform Abstract: MECHANISM AND LINEAR FREE ENERGY RELATIONSHIPS IN THE KINETICS OF FORMATION OF BICYCLO(3.3.1)NONANE DERIVATIVES FROM 1,3,5-TRINITROBENZENE, BENZOYLACETONES, AND BASE

1985 ◽  
Vol 16 (34) ◽  
Author(s):  
L. M. GNANADOSS ◽  
D. KALAIVANI
2020 ◽  
Vol 18 (11) ◽  
pp. 2113-2119 ◽  
Author(s):  
Mads Mansø ◽  
Anne Ugleholdt Petersen ◽  
Kasper Moth-Poulsen ◽  
Mogens Brøndsted Nielsen

The kinetics of the thermal quadricyclane-to-norbornadiene (QC-to-NBD) isomerization follows a linear-free-energy relationship when using Creary radical values for a selection of aryl/cyano disubstituted derivatives.


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