Speed of Sound, Isentropic Compressibility, Viscosity, and Excess Volume of Binary Mixtures. 1. Alkanenitriles with Alkyl Acetates

1995 ◽  
Vol 40 (4) ◽  
pp. 840-844 ◽  
Author(s):  
S. L. Oswal ◽  
N. B. Patel
Keyword(s):  
Binary Mixtures ◽  
Speed Of Sound ◽  
Excess Volume ◽  
Isentropic Compressibility ◽  
Alkyl Acetates

scholarly journals Studies on Excess Volume, Viscosity, and Speed of Sound of Binary Mixtures of Methyl Benzoate in Ethers at T=(303.15,308.15, and 313.15) K

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
M. V. Rathnam ◽  
Devappa R. Ambavadekar ◽  
M. Nandini
Keyword(s):  
Binary Mixtures ◽  
Speed Of Sound ◽  
Entire Range ◽  
Binary Data ◽  
Excess Volume ◽  
Binary Systems ◽  
Isentropic Compressibility ◽  
Methyl Benzoate ◽  
Volume Viscosity ◽  
Gibb’S Free Energy

Densities, viscosities, and speed of sound have been determined at T = (303.15, 308.15, and 313.15) K for the binary mixtures of methyl benzoate with tetrahydrofuran, 1,4-dioxane, anisole, and butyl vinyl ether over the entire range of composition. Using these measured values, excess volume VE, deviation in viscosities Δη, excess Gibb’s free energy of activation for viscous flow ΔG*E, and deviation in isentropic compressibility Δks have been calculated. These calculated binary data have been fitted to Redlich-Kister equation to determine the appropriate coefficients. The values of excess volume VE and deviation in viscosities Δη are negative over the entire range of composition for all the binary systems at the studied temperatures. The behavior of these parameters with composition of the mixture has been discussed in terms of molecular interactions between the components of liquids.

scholarly journals Thermophysical Properties of Binary Mixtures of Dimethylsulfoxide with 1-Phenylethanone and 1,4-Dimethylbenzene at Various Temperatures

2014 ◽  
Vol 2014 ◽  
pp. 1-9
Author(s):  
Harmandeep Singh Gill ◽  
V. K. Rattan
Keyword(s):  
Binary Mixtures ◽  
Speed Of Sound ◽  
Atmospheric Pressure ◽  
Composition Range ◽  
Excess Molar Volumes ◽  
Isentropic Compressibility ◽  
Molar Refraction ◽  
Viscosity Deviations ◽  
Research Article ◽  
Kister Equation

This research article reports the experimental results of the density, viscosity, refractive index, and speed of sound analysis of binary mixtures of dimethylsulfoxide (DMSO) + 1-phenylethanone (acetophenone) and + 1,4-dimethylbenzene (para-xylene) over the whole composition range at 313.15, 318.15, 323.15, and 328.15 K and at atmospheric pressure. The excess molar volumes (VE), viscosity deviations (Δη), excess Gibbs energy of activation (GE), deviations in isentropic compressibility (KSE), deviations in speed of sound (uE), and deviations in the molar refraction (ΔR) were calculated from the experimental data. The computed quantities were fitted to the Redlich-Kister equation to derive the coefficients and estimate the standard error values. The viscosities have also been correlated with two, and three-parameter models, that is, Heric correlation, McAllister model, and Grunberg-Nissan correlation, respectively.

Sign in / Sign up

Export Citation Format

Share Document