Speed of Sound and Excess Isentropic Compressibility of 1,3-Dioxolane or 1,4-Dioxane + Butan-1-ol or + Butan-2-ol Binary Mixtures at 308.15 K and Atmospheric Pressure

2010 ◽  
Vol 49 (18) ◽  
pp. 8365-8368 ◽  
Author(s):  
Satish Kumar ◽  
V. K. Sharma ◽  
Il Moon
Keyword(s):  
Binary Mixtures ◽  
Speed Of Sound ◽  
Atmospheric Pressure ◽  
Isentropic Compressibility ◽  
Excess Isentropic Compressibility

scholarly journals Thermophysical Properties of Binary Mixtures of Dimethylsulfoxide with 1-Phenylethanone and 1,4-Dimethylbenzene at Various Temperatures

2014 ◽  
Vol 2014 ◽  
pp. 1-9
Author(s):  
Harmandeep Singh Gill ◽  
V. K. Rattan
Keyword(s):  
Binary Mixtures ◽  
Speed Of Sound ◽  
Atmospheric Pressure ◽  
Composition Range ◽  
Excess Molar Volumes ◽  
Isentropic Compressibility ◽  
Molar Refraction ◽  
Viscosity Deviations ◽  
Research Article ◽  
Kister Equation

This research article reports the experimental results of the density, viscosity, refractive index, and speed of sound analysis of binary mixtures of dimethylsulfoxide (DMSO) + 1-phenylethanone (acetophenone) and + 1,4-dimethylbenzene (para-xylene) over the whole composition range at 313.15, 318.15, 323.15, and 328.15 K and at atmospheric pressure. The excess molar volumes (VE), viscosity deviations (Δη), excess Gibbs energy of activation (GE), deviations in isentropic compressibility (KSE), deviations in speed of sound (uE), and deviations in the molar refraction (ΔR) were calculated from the experimental data. The computed quantities were fitted to the Redlich-Kister equation to derive the coefficients and estimate the standard error values. The viscosities have also been correlated with two, and three-parameter models, that is, Heric correlation, McAllister model, and Grunberg-Nissan correlation, respectively.

scholarly journals A Comparison Study on Molecular Interaction of an Acidic Organophosphoric Extractant with Substituted Aromatic Hydrocarbon (p-xylene/toluene) at 303.15K

2020 ◽  
Vol 11 (3) ◽  
pp. 10052-10058
Keyword(s):  
Binary Mixtures ◽  
Ultrasonic Velocity ◽  
Aromatic Hydrocarbons ◽  
Molecular Interaction ◽  
Atmospheric Pressure ◽  
Composition Range ◽  
Isentropic Compressibility ◽  
Extraction Process ◽  
Comparison Study ◽  
Intermolecular Free Length

In the present study, the excess molar volume (VE) and the deviations in intermolecular free length (ΔLf), isentropic compressibility (Δβs), acoustic impedance (ΔZ), and ultrasonic velocity (ΔU) were calculated using the experimentally measured values of density (ρ) and ultrasonic velocity (U) of binary mixtures of an acidic organophosphoric extractant (DEHPA) with two substituted aromatic hydrocarbons, i.e., p-xylene and toluene at 303.15K and atmospheric pressure, 0.1MPa over the entire composition range of DEHPA. The results of both binary mixtures have been presented graphically and compared in terms of molecular interaction between unlike molecules of the mixtures, which outcome may be applied in the solvent extraction process.

scholarly journals Thermo Physical Properties for Binary Mixture of Dimethylsulfoxide and Isopropylbenzene at Various Temperatures

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Maninder Kumar ◽  
V. K. Rattan
Keyword(s):  
Refractive Index ◽  
Binary Mixture ◽  
Speed Of Sound ◽  
Excess Molar Volume ◽  
Atmospheric Pressure ◽  
Composition Range ◽  
Isentropic Compressibility ◽  
Experimental Measurements ◽  
Kister Equation ◽  
Thermo Physical Properties

Density, refractive index, speed of sound, and viscosity have been measured of binary mixture dimethylsulfoxide (DMSO) + isopropylbenzene (CUMENE) over the whole composition range at 298.15, 303.15, 308.15, and 313.15 K and atmospheric pressure. From these experimental measurements the excess molar volume, deviations in viscosity, molar refractivity, speed of sound, and isentropic compressibility have been calculated. These deviations have been correlated by a polynomial Redlich-Kister equation to derive the coefficients and standard error. The viscosities have furthermore been correlated with two or three parameter models, that is, herric correlation and McAllister model, respectively.

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