Convergent Total Synthesis of Hikizimycin Enabled by Intermolecular Radical Addition to Aldehyde

2020 ◽  
Vol 142 (30) ◽  
pp. 13227-13234 ◽  
Author(s):  
Haruka Fujino ◽  
Takumi Fukuda ◽  
Masanori Nagatomo ◽  
Masayuki Inoue
Keyword(s):  
Total Synthesis ◽  
Radical Addition

Total Synthesis of (−)-Martinellic Acid via Radical Addition−Cyclization−Elimination Reaction

2008 ◽  
Vol 73 (12) ◽  
pp. 4464-4475 ◽  
Author(s):  
Atsushi Shirai ◽  
Okiko Miyata ◽  
Norimitsu Tohnai ◽  
Mikiji Miyata ◽  
David J. Procter ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Radical Addition ◽  
Elimination Reaction ◽  
Martinellic Acid

Heterocycle synthesis via radical reactions

2008 ◽  
Vol 80 (4) ◽  
pp. 717-726 ◽  
Author(s):  
Takeaki Naito
Keyword(s):  
Total Synthesis ◽  
Heterocyclic Compounds ◽  
Alkyl Radical ◽  
Radical Addition ◽  
Synthetic Method ◽  
Asymmetric Total Synthesis ◽  
Heterocycle Synthesis ◽  
Leaving Group ◽  
Martinellic Acid ◽  
Type Radical

A novel synthetic method for the preparation of nitrogen-containing heterocycles via the route involving domino-type radical addition/cyclization reaction of oxime ethers is described. Alkyl radical addition/cyclization of oxime ethers carrying an appropriate leaving group proceeded smoothly to form the alkylated nitrogen-containing heterocyclic compounds. Additionally, tin-mediated radical addition/cyclization/elimination (RACE) reaction of oxime ethers is newly found and successfully applied to an asymmetric total synthesis of (-)-martinellic acid.

scholarly journals Correction to “Total Synthesis of (−)-Chromodorolide B By a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade”

2018 ◽  
Vol 141 (1) ◽  
pp. 706-706
Author(s):  
Daniel J. Tao ◽  
Yuriy Slutskyy ◽  
Mikko Muuronen ◽  
Alexander Le ◽  
Philipp Kohler ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Radical Addition

Total Synthesis of 10-Norparvulenone and ofO-Methylasparvenone Using a Xanthate-Mediated Free Radical Addition−Cyclization Sequence

2003 ◽  
Vol 5 (20) ◽  
pp. 3717-3719 ◽  
Author(s):  
Alejandro Cordero Vargas ◽  
Béatrice Quiclet-Sire ◽  
Samir Z. Zard
Keyword(s):  
Free Radical ◽  
Total Synthesis ◽  
Radical Addition ◽  
Free Radical Addition
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