Dinitrogen Cleavage by a Heterometallic Cluster Featuring Multiple Uranium–Rhodium Bonds

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The reaction of the N-heterocyclic carbene stabilized complex [(IPr)Cu–SSiMe3] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with mercuric(ii) acetate affords the heterometallic cluster [{(IPr)CuS}2Hg] (illustrated).


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