Simple but effective: thermally stable Cu–ESiMe3via NHC ligation

2015 ◽  
Vol 51 (39) ◽  
pp. 8361-8364 ◽  
Author(s):  
Mahmood Azizpoor Fard ◽  
Florian Weigend ◽  
John F. Corrigan
Keyword(s):  
Thermally Stable ◽  
Heterometallic Cluster

The reaction of the N-heterocyclic carbene stabilized complex [(IPr)Cu–SSiMe3] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with mercuric(ii) acetate affords the heterometallic cluster [{(IPr)CuS}2Hg] (illustrated).

Investigation of the V4+-Centre in 6H- and 4H-SIC by the Method of Spectral-Hole Burning

1998 ◽  
Vol 512 ◽  
Author(s):  
C. Hecht ◽  
R. Kummer ◽  
A. Winnacker
Keyword(s):  
Electronic Properties ◽  
Room Temperature ◽  
Hole Burning ◽  
Band Offset ◽  
Spectral Hole Burning ◽  
Type Ii ◽  
Thermally Stable ◽  
Spectral Hole

ABSTRACTIn the context of spectral-hole burning experiments in 4H- and 6H-SiC doped with vanadium the energy positions of the V4+/5+ level in both polytypes were determined in order to resolve discrepancies in literature. From these numbers the band offset of 6H/4H-SiC is calculated by using the Langer-Heinrich rule, and found to be of staggered type II. Furthermore the experiments show that thermally stable electronic traps exist in both polytypes at room temperature and considerably above, which may result in longtime transient shifts of electronic properties.

Advanced Thermally Stable Jet Fuels Development Program Annual Report. Volume 1. Model and Experiment System Development

1990 ◽  
Author(s):  
Elmer Klavetter ◽  
Tim O'Hern ◽  
Bill Marshall ◽  
Merrill Jr. ◽  
Frye Ray ◽  
...  
Keyword(s):  
Annual Report ◽  
System Development ◽  
Development Program ◽  
Jet Fuels ◽  
Thermally Stable ◽  
Experiment System

Acetylene chemisorption at palladium: Effect of temperature and structure of the surface

1984 ◽  
Vol 49 (6) ◽  
pp. 1448-1458
Author(s):  
Josef Kopešťanský
Keyword(s):  
Work Function ◽  
Atomic Hydrogen ◽  
Effect Of Temperature ◽  
Thermally Stable ◽  
Template Effect ◽  
Temperature Range ◽  
Adsorbed Layers ◽  
Different Types ◽  
Adsorption Complexes ◽  
Low Coverage

The effect of temperature and structure of the palladium surfaces on acetylene chemisorption was studied along with the interaction of the adsorbed layers with molecular and atomic hydrogen. The work function changes were measured and combined with the volumetric measurements and analysis of the products. At temperature below 100 °C, acetylene is adsorbed almost without dissociation and forms at least two different types of thermally stable adsorption complexes. Acetylene adsorbed at 200 °C is partly decomposed, especially in the low coverage region. Besides the above mentioned effects, the template effect of adsorbed acetylene was studied in the temperature range from -80° to 25 °C. It has been shown that this effect is a typical phenomenon of the palladium-acetylene system which is not due to surface impurities.

Thermally Stable Half-Sandwich Benzhydryl Ln(II) (Ln = Sm, Yb) Complexes Supported by Sterically Demanding Carbazolyl and Fluorenyl Ligands

2019 ◽  
Vol 38 (24) ◽  
pp. 4615-4624 ◽  
Author(s):  
Alexander N. Selikhov ◽  
Andrey S. Shavyrin ◽  
Anton V. Cherkasov ◽  
Georgy K. Fukin ◽  
Alexander A. Trifonov
Keyword(s):  
Thermally Stable ◽  
Sterically Demanding ◽  
Half Sandwich

Exceptionally Stable Sol-immobilization Derived Pd/SBA-15 Catalyst for Methane Combustion

2021 ◽  
Author(s):  
Ramana Murthy Palle ◽  
Jing-Cai Zhang ◽  
Wei-Zhen Li
Keyword(s):  
High Temperatures ◽  
Methane Combustion ◽  
Thermally Stable ◽  
Sintering Effect

Pd-based catalysts are efficient for methane combustion but impractical at high temperatures due to sintering effect. Here in, we report a thermally stable Pd/SBA-15 catalyst that was prepared by using...

scholarly journals Organocatalyzed closed-loop chemical recycling of thermo-compressed films of poly(ethylene furanoate)

2021 ◽  
Author(s):  
Elena Gabirondo ◽  
Beatriz Melendez-Rodriguez ◽  
Carmen Arnal ◽  
Jose M. Lagaron ◽  
Antxon Martínez de Ilarduya ◽  
...  
Keyword(s):  
Closed Loop ◽  
Chemical Recycling ◽  
Thermally Stable ◽  
Poly Ethylene

Poly(ethylene furanoate) (PEF) films were first produced using thermo-compression. Thereafter, the chemical recyclability was demonstrated in the presence of a thermally stable organocatalyst followed by its repolymerization.

Synthesis of highly thermally stable divanillic acid-derived polyamides and their mechanical properties

Polymer ◽  
2021 ◽  
pp. 123907
Author(s):  
Kazuma Yagura ◽  
Yunfan Zhang ◽  
Yukiko Enomoto ◽  
Tadahisa Iwata
Keyword(s):  
Mechanical Properties ◽  
Thermally Stable

Thermally stable amine-functionalized silica sorbents using one-pot synthesis method for CO2 capture at low temperature

2020 ◽  
Vol 37 (12) ◽  
pp. 2317-2325
Author(s):  
Seong Bin Jo ◽  
Ho Jin Chae ◽  
Tae Young Kim ◽  
Jeom-In Baek ◽  
Dhanusuraman Ragupathy ◽  
...  
Keyword(s):  
Low Temperature ◽  
Co2 Capture ◽  
Synthesis Method ◽  
Functionalized Silica ◽  
Thermally Stable ◽  
One Pot ◽  
One Pot Synthesis ◽  
Amine Functionalized
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