Carbon Monoxide-Induced Dinitrogen Cleavage with Group 4 Metallocenes: Reaction Scope and Coupling to N−H Bond Formation and CO Deoxygenation

2010 ◽  
Vol 132 (30) ◽  
pp. 10553-10564 ◽  
Author(s):  
Donald J. Knobloch ◽  
Emil Lobkovsky ◽  
Paul J. Chirik
Keyword(s):  
Carbon Monoxide ◽  
Bond Formation ◽  
Group 4 ◽  
Dinitrogen Cleavage

scholarly journals Carbon Monoxide Activation by a Molecular Aluminium Imide: C−O Bond Cleavage and C−C Bond Formation

2020 ◽  
Vol 59 (12) ◽  
pp. 4897-4901 ◽  
Author(s):  
Andreas Heilmann ◽  
Jamie Hicks ◽  
Petra Vasko ◽  
Jose M. Goicoechea ◽  
Simon Aldridge
Keyword(s):  
Carbon Monoxide ◽  
Bond Cleavage ◽  
Bond Formation

ChemInform Abstract: CARBON MONOXIDE ACTIVATION BY BISCYCLOPENTADIENYL COMPLEXES OF GROUP 4 METALS AND ACTINIDES: η2-ACYL COMPLEXES

1985 ◽  
Vol 16 (45) ◽  
Author(s):  
K. TATSUMI ◽  
A. NAKAMURA ◽  
P. HOFMANN ◽  
P. STAUFFERT ◽  
R. HOFFMANN
Keyword(s):  
Carbon Monoxide ◽  
Acyl Complexes ◽  
Group 4 ◽  
Group 4 Metals

Fischer-Tropsch CO-Hydrogenation on SiO2-supported Osmium Complexes

2008 ◽  
Vol 63 (3) ◽  
pp. 289-292 ◽  
Author(s):  
Ntombovuyo Bungane ◽  
Cathrin Welker ◽  
Eric van Steen ◽  
Michael Claeys
Keyword(s):  
Carbon Monoxide ◽  
Co Hydrogenation ◽  
Bond Formation ◽  
Organometallic Complexes ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
High Olefin ◽  
Osmium Complexes ◽  
Very High

The conversion of carbon monoxide with hydrogen was studied on a standard Os on SiO2 catalyst at different reaction temperatures, in the range between 200 and 300 °C. Additionally, supported di- and triatomic organometallic Os complexes were tested for their activity in the Fischer-Tropsch synthesis at 220 °C. All compounds showed formation of hydrocarbons, indicating that the organoosmium complexes are indeed active for C─C bond formation. Osmium as Fischer-Tropsch catalyst, however, is approximately 100 times less active compared to ruthenium. Very high methane selectivities (> 90 C-%) were obtained as well as high olefin to paraffin ratios, in particular with the organometallic complexes tested.

Reaction of electron-deficient Group 4 metal s-cis-butadiene complexes with carbon monoxide

1989 ◽  
Vol 8 (12) ◽  
pp. 2809-2812 ◽  
Author(s):  
Bart. Hessen ◽  
Joop. Blenkers ◽  
Jan H. Teuben ◽  
Goeran. Helgesson ◽  
Susan. Jagner
Keyword(s):  
Carbon Monoxide ◽  
Group 4 ◽  
Group 4 Metal ◽  
Deficient Group

Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex

2009 ◽  
Vol 2 (1) ◽  
pp. 30-35 ◽  
Author(s):  
Donald J. Knobloch ◽  
Emil Lobkovsky ◽  
Paul J. Chirik
Keyword(s):  
Carbon Monoxide ◽  
Dinitrogen Cleavage
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