Supramolecular Organization of Oligo(m-phenylene ethynylene)s in the Solid-State

1999 ◽  
Vol 121 (25) ◽  
pp. 5933-5939 ◽  
Author(s):  
Peggy-Jean Prest ◽  
Ryan B. Prince ◽  
Jeffrey S. Moore
Keyword(s):  
Solid State ◽  
Supramolecular Organization ◽  
Phenylene Ethynylene

scholarly journals Insights into the Photophysics and Supramolecular Organization of Congo Red in Solution and the Solid State

ChemPhysChem ◽  
2017 ◽  
Vol 18 (5) ◽  
pp. 564-575 ◽  
Author(s):  
Ana L. Costa ◽  
Ana C. Gomes ◽  
Martyn Pillinger ◽  
Isabel S. Gonçalves ◽  
João Pina ◽  
...  
Keyword(s):  
Solid State ◽  
Congo Red ◽  
Supramolecular Organization

Solid-State Chiral Supramolecular Organic Fluorophore Having a π-Conjugated Phenylene Ethynylene Unit

2009 ◽  
Vol 2009 (33) ◽  
pp. 5760-5764 ◽  
Author(s):  
Takafumi Kinuta ◽  
Kensaku Kamon ◽  
Takunori Harada ◽  
Yoko Nakano ◽  
Nobuo Tajima ◽  
...  
Keyword(s):  
Solid State ◽  
Phenylene Ethynylene ◽  
Organic Fluorophore

Synthesis and Solid-State Investigations of Oligo-Phenylene-Ethynylene Structures with Halide End-Groups

2012 ◽  
Vol 2012 (14) ◽  
pp. 2738-2747 ◽  
Author(s):  
Nicolas M. Jenny ◽  
Hong Wang ◽  
Markus Neuburger ◽  
Harald Fuchs ◽  
Lifeng Chi ◽  
...  
Keyword(s):  
Solid State ◽  
Phenylene Ethynylene ◽  
End Groups

Supramolecular Organization and Evaporation of Polymeric Tin Trifluoroacetates

2019 ◽  
Author(s):  
Goran Bacic ◽  
Conor D. Rankine ◽  
Jason D. Masuda ◽  
Derek A. Wann ◽  
Sean Barry
Keyword(s):  
Thermal Stability ◽  
Solid State ◽  
Density Functional ◽  
Chemical Vapor ◽  
Atomic Layer ◽  
Building Blocks ◽  
Supramolecular Organization ◽  
Layer Deposition ◽  
Earth Abundant ◽  
Green Potential

<div> <div> <div> <p>Simple tin carboxylates make up a family of important industrial catalysts and precursors for deposition of SnO2 thin films. However, their structures remain disparately characterized, and tin trifluoroacetates have been particularly elusive. Here we report on a combined X-ray diffraction (XRD), gas phase electron diffraction (GED) and density functional theory (DFT) study into the structure and bonding of tin(II) and tin(IV) trifluoroacetates to understand their influence on thermal stability and volatility. Tin(II) bis(trifluoroacetate) (1′) eliminates trifluoroacetic anhydride upon sublimation to form the linear polymeric hexatin(II)-di-μ -oxy-octakis-μ-trifluoroacetate (1F ), which itself sublimes (1 Torr at 191 C) as a 1:1 mixture of 1 and ditin(II)-μ-oxy-bis-μ-trifluoroacetate (1′′). Tin(IV) tetrakis(trifluoroacetate) (2F) is also polymeric in the solid state, but evaporates as a monomer at low temperatures (1 Torr at 84 ◦C). Together they make a family of multifunctional Lewis acidic and basic building blocks for supramolecular organization of clusters and polymers in the solid state. Anomalous trends in the volatility of these trifluoroacetates and their hydrogenated derivatives can be rationalized by consideration of their modes of polymerization with respect to the thermodynamics of evaporation. Both 1F and 2F combine high thermal stability and volatility, and are demonstrated to be complementary, safe, and green potential precursors for chemical vapor deposition (CVD) or atomic layer deposition (ALD) of earth-abundant transparent conducting F-doped SnO2. </p> <div><div><div> <p> </p> </div> </div> </div> </div> </div> </div>

Temperature dependence of charge transport in solid-state molecular junctions based on oligo(phenylene ethynylene)s

2020 ◽  
Vol 31 (16) ◽  
pp. 164001
Author(s):  
Yuqing Liu ◽  
Mianzeng Zhong ◽  
Elisabeth Ffion Downey ◽  
Xiaoyao Chen ◽  
Tao Li ◽  
...  
Keyword(s):  
Solid State ◽  
Charge Transport ◽  
Temperature Dependence ◽  
Molecular Junctions ◽  
Phenylene Ethynylene

Solid-State Supramolecular Organization of Polythiophene Chains Containing Thienothiophene Units

2009 ◽  
Vol 21 (10-11) ◽  
pp. 1193-1198 ◽  
Author(s):  
Patrick Brocorens ◽  
Antoine Van Vooren ◽  
Michael L. Chabinyc ◽  
Michael F. Toney ◽  
Maxim Shkunov ◽  
...  
Keyword(s):  
Solid State ◽  
Supramolecular Organization

scholarly journals Synthesis, characterization and solid-state photoluminescence studies of six alkoxy phenylene ethynylene dinuclear palladium(ii) rods

2015 ◽  
Vol 44 (9) ◽  
pp. 4003-4015 ◽  
Author(s):  
João Figueira ◽  
Wojciech Czardybon ◽  
José Carlos Mesquita ◽  
João Rodrigues ◽  
Fernando Lahoz ◽  
...  
Keyword(s):  
Solid State ◽  
Emission Intensity ◽  
Phenylene Ethynylene ◽  
Pd Complexes ◽  
Photoluminescence Studies

Solid-state photoluminescence studies of six dinuclear [PdCl(PEt3)2]) rods revealed a decrease in the emission intensity when moving from the free ligands to the Pd complexes.

Photoexcitations in Oligothiophenes: The Role of Conformation Mobility and Intermolecular Interactions.

1999 ◽  
Vol 598 ◽  
Author(s):  
Chiara Botta ◽  
Silvia Destri ◽  
William Porzio ◽  
Gianni Bongiovanni ◽  
Andrea Mura ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Intermolecular Interactions ◽  
Photophysical Properties ◽  
Supramolecular Organization ◽  
Relaxation Processes ◽  
Chain Packing ◽  
Backbone Conformation ◽  
Packing Arrangement

ABSTRACTThe optical properties of substituted and unsubstituted oligothiophenes are analysed with respect to their supramolecular organization in the solid state. The spectra typical of the isolated molecules are obtained by reducing the intermolecular interactions by both lateral chain substitution and by inclusion in a host organic crystal. The photophysical properties of the weakly interacting oligothiophenes are strongly influenced by their backbone conformation and conformational mobility. Oligomers included in the channels of a guest crystal show fast torsional relaxation processes during the photoexcitation. Powders of β-substituted oligomers display optical properties dependent on the conformation of their particular chain packing arrangement.

scholarly journals Supramolecular Chirogenesis in Bis-Porphyrin: Crystallographic Structure and CD Spectra for a Complex with a Chiral Guanidine Derivative

Symmetry ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 275
Author(s):  
Irina Osadchuk ◽  
Nele Konrad ◽  
Khai-Nghi Truong ◽  
Kari Rissanen ◽  
Eric Clot ◽  
...  
Keyword(s):  
Solid State ◽  
Computational Simulation ◽  
Spatial Arrangement ◽  
Crystallographic Structure ◽  
Supramolecular Organization ◽  
Cd Spectra ◽  
X Ray Diffraction ◽  
Guest Complex ◽  
X Ray ◽  
Host Guest Complex

The complexation of (3aR,7aR)-N-(3,5-bis(trifluoromethyl)phenyl)octahydro-2H-benzo[d]imidazol-2-imine (BTI), as a guest, to ethane-bridged bis(zinc octaethylporphyrin), bis(ZnOEP), as a host, has been studied by means of ultraviolet-visible (UV-Vis) and circular dichroism (CD) absorption spectroscopies, single crystal X-ray diffraction, and computational simulation. The formation of 1:2 host-guest complex was established by X-ray diffraction and UV-Vis titration studies. Two guest BTI molecules are located at the opposite sides of two porphyrin subunits of bis(ZnOEP) host, which is resting in the anti-conformation. The complexation of BTI molecules proceed via coordination of the imine nitrogens to the zinc ions of each porphyrin subunit of the host. Such supramolecular organization of the complex results in a screw arrangement of the two porphyrin subunits, inducing a strong CD signal in the Soret (B) band region. The corresponding DFT computational studies are in a good agreement with the experimental results and prove the presence of 1:2 host-guest complex as the major component in the solution (97.7%), but its optimized geometry differs from that observed in the solid-state. The UV-Vis and CD spectra simulated by using the solution-state geometry and the TD-DFT/ωB97X-D/cc-pVDZ + SMD (CH2Cl2) level of theory reproduced the experimentally obtained UV-Vis and CD spectra and confirmed the difference between the solid-state and solution structures. Moreover, it was shown that CD spectrum is very sensitive to the spatial arrangement of porphyrin subunits.

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