The Chemical Vapor Deposition of Aluminum Nitride:  Unusual Cluster Formation in the Gas Phase

1997 ◽  
Vol 119 (24) ◽  
pp. 5668-5678 ◽  
Author(s):  
Alexey Y. Timoshkin ◽  
Holger F. Bettinger ◽  
Henry F. Schaefer
2001 ◽  
Vol 542 (1-3) ◽  
pp. 239-246 ◽  
Author(s):  
Xiao-Hong Xu ◽  
Hai-Shun Wu ◽  
Fu-Qiang Zhang ◽  
Cong-Jie Zhang ◽  
Zhi-Hao Jin

1988 ◽  
Vol 131 ◽  
Author(s):  
Wayne L. Gladfelter ◽  
David C. Boyd ◽  
Jen-WeI Hwang ◽  
Richard T. Haasch ◽  
John F. Evans ◽  
...  

ABSTRACTOrganometallic aluminum azides have been found to be effective precursors for the low temperature chemical vapor deposition of thin films of aluminum nitride. Quantitative analysis of the gas phase products of the reaction are used to develop an understanding of the reaction. Rate studies of the deposition were performed in the temperature range from 400 to 800°C. Below 525°C, an activation barrier of 26.4 kcal/mol was found, while above 525°C, a value of 5.23 kcal/mol was obtained. The effects of the presence of N-C bonds and the type of Al-N interaction within the precursor are evaluated.


2017 ◽  
Vol 121 (47) ◽  
pp. 26465-26471 ◽  
Author(s):  
Mewlude Imam ◽  
Laurent Souqui ◽  
Jan Herritsch ◽  
Andreas Stegmüller ◽  
Carina Höglund ◽  
...  

Author(s):  
Sebastian Grimm ◽  
Seung-Jin Baik ◽  
Patrick Hemberger ◽  
Andras Bodi ◽  
Andreas Kempf ◽  
...  

Although aluminium acetylacetonate, Al(C5H7O2)3, is a common precursor for chemical vapor deposition (CVD) of aluminium oxide, its gas phase decomposition is not very well investigated. Here, we studied its thermal...


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