scholarly journals Cation exchange at the secondary building units of metal–organic frameworks

2014 ◽  
Vol 43 (16) ◽  
pp. 5456-5467 ◽  
Author(s):  
C. K. Brozek ◽  
M. Dincă
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

This review examines the governing factors of cation exchange at the secondary building units of MOFs and reviews its applications.

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

ChemInform Abstract: Secondary Building Units, Nets and Bonding in the Chemistry of Metal-Organic Frameworks

ChemInform ◽  
2009 ◽  
Vol 40 (29) ◽  
Author(s):  
David J. Tranchemontagne ◽  
Jose L. Mendoza-Cortes ◽  
Michael O'Keeffe ◽  
Omar M. Yaghi
Keyword(s):  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

Intrinsic White‐Light‐Emitting Metal–Organic Frameworks with Structurally Deformable Secondary Building Units

2019 ◽  
Vol 58 (23) ◽  
pp. 7818-7822 ◽  
Author(s):  
Chengdong Peng ◽  
Xueling Song ◽  
Jinlin Yin ◽  
Guiyang Zhang ◽  
Honghan Fei
Keyword(s):  
White Light ◽  
Metal Organic Frameworks ◽  
Light Emitting ◽  
Secondary Building Units ◽  
Metal Organic

Accurate tuning of rare earth metal–organic frameworks with unprecedented topology for white-light emission

2020 ◽  
Vol 8 (4) ◽  
pp. 1374-1379 ◽  
Author(s):  
Yutong Wang ◽  
Kai Zhang ◽  
Xiaokang Wang ◽  
Xuelian Xin ◽  
Xiurong Zhang ◽  
...  
Keyword(s):  
White Light ◽  
Light Emission ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Earth Metal ◽  
White Light Emission ◽  
One Dimensional ◽  
1D Chain ◽  
Secondary Building Units ◽  
Metal Organic

An unprecedented three-dimensional (3D) (3,4,5)-czkf topological framework (UPC-38) with one-dimensional (1D) chain secondary building units exhibits strong white light emission.

Ammonia Capture within Isoreticular Metal–Organic Frameworks with Rod Secondary Building Units

2019 ◽  
Vol 1 (4) ◽  
pp. 476-480 ◽  
Author(s):  
Shinya Moribe ◽  
Zhijie Chen ◽  
Selim Alayoglu ◽  
Zoha H. Syed ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

Four novel Co(II) metal-organic frameworks based on semi-rigid ligand and their secondary building units transformation

2019 ◽  
Vol 1197 ◽  
pp. 87-95 ◽  
Author(s):  
Lili Fan ◽  
Xiaobin Liu ◽  
Liangliang Zhang ◽  
Xia Kong ◽  
Zhenyu Xiao ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

scholarly journals Two-dimensional metal-organic frameworks containing linear dicarboxylates

2006 ◽  
Vol 62 (5) ◽  
pp. 808-814 ◽  
Author(s):  
Samuel M. Hawxwell ◽  
Harry Adams ◽  
Lee Brammer
Keyword(s):  
Dicarboxylic Acid ◽  
Solvothermal Synthesis ◽  
Interplanar Spacing ◽  
Metal Organic Frameworks ◽  
Dicarboxylic Acids ◽  
Two Dimensional ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Gas Molecules ◽  
Solvent Molecules

The solvothermal synthesis of four two-dimensional metal-organic frameworks containing linear dicarboxylic acids as ligands for ZnII centres is described. Zn(BDC)(DMF) [(1) where BDC = benzene-1,4-dicarboxylic acid; DMF = N,N-dimethylformamide] adopts a common paddlewheel motif leading to a 44 grid network, whereas Zn3(BDC)3(EtOH)2 (2), Zn3(BDC)3(H2O)2·4DMF (3) and Zn3(BPDC)3(DMF)2·4DMF (4) each form networks with the relatively uncommon 36 topology based upon Zn3(O2CR)6 secondary building units. All contain coordinated solvent molecules, namely DMF [(1) and (4)], ethanol (2) or H2O (3). Comparison of structures (2) and (3) illustrates a clay-like flexibility in interplanar spacing which sheds light on the ability of the Zn3(BDC)3 framework to undergo desolvation and uptake of small solvent and gas molecules.

scholarly journals Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis

2012 ◽  
Vol 468 (2143) ◽  
pp. 2035-2052 ◽  
Author(s):  
Feijie Song ◽  
Teng Zhang ◽  
Cheng Wang ◽  
Wenbin Lin
Keyword(s):  
Asymmetric Catalysis ◽  
Active Sites ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Dicarboxylic Acids ◽  
Great Promise ◽  
Epoxide Ring ◽  
Potential Applications ◽  
Secondary Building Units ◽  
Metal Organic

Metal-organic frameworks (MOFs) are a class of organic–inorganic hybrid materials built from metal-connecting nodes and organic-bridging ligands. They have received much attention in recent years owing to the ability to tune their properties for potential applications in various areas. Properly designed MOFs with uniform, periodically aligned active sites have shown great promise in catalysing shape-, size-, chemo-, regio- and stereo-selective organic transformations. This study reports the synthesis and characterization of two chiral MOFs (CMOFs 1 and 2 ) that are constructed from Mn-salen-derived dicarboxylic acids [salen is ( R , R )- N , N ′-bis(5- tert -butylsalicylidene)-1,2-cyclohexanediamine], bis(4-vinylbenzoic acid)-salen manganese(III) chloride (H 2 L 4 ) or bis(benzoic acid)-salen manganese(III) chloride (H 2 L 3 ) and [Zn 4 (μ 4 -O)(O 2 CR) 6 ] or [Zn 5 (H 2 O) 2 (μ 3 -OH) 2 (O 2 CR) 8 ] secondary building units (SBUs), respectively. The SBUs in CMOF- 1 are connected by the linear ditopic Mn-salen-derived linkers to construct a fourfold interpenetrated isoreticular MOF (IRMOF) structure with pcu topology. In CMOF- 2 , the Mn-salen centres dimerize in a cross-linking way to form a diamondoid structure with threefold interpenetration. CMOF- 1 was examined for highly regio- and stereo-selective tandem alkene epoxidation/epoxide ring-opening reactions by using the Mn-salen andZn 4 (μ 4 -O)(carboxylate) 6 active sites, respectively. Our work demonstrated the potential utility of chiral MOFs with multiple active sites in the efficient synthesis of complex molecules with excellent regio- and stereo-controls

Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks

2012 ◽  
Vol 134 (43) ◽  
pp. 18082-18088 ◽  
Author(s):  
Min Kim ◽  
John F. Cahill ◽  
Honghan Fei ◽  
Kimberley A. Prather ◽  
Seth M. Cohen
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Metal Organic
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