scholarly journals Advancing the Mechanistic Understanding of an Enantioselective Palladium-Catalyzed Alkene Difunctionalization Reaction

2010 ◽  
Vol 132 (49) ◽  
pp. 17471-17482 ◽  
Author(s):  
Katrina H. Jensen ◽  
Jonathan D. Webb ◽  
Matthew S. Sigman
Keyword(s):  
Palladium Catalyzed ◽  
Mechanistic Understanding ◽  
Alkene Difunctionalization

scholarly journals Mechanistic Understanding Enables Chemoselective sp3 over sp2 C-H Activation in Pd-Catalyzed Carbonylative Cyclization of Amino Acids

2021 ◽  
Author(s):  
Mario Martinez-Mingo ◽  
Ines Alonso ◽  
Nuria Rodriguez ◽  
Ramon Gomez Arrayas ◽  
Juan Carlos Carretero
Keyword(s):  
Amino Acids ◽  
Palladium Catalyzed ◽  
Mechanistic Understanding ◽  
Activation Pathways

Mechanistic insights into the factors that control chemoselectivity in competing C(sp2)-H and C(sp3)-H activation pathways in the palladium-catalyzed carbonylative cyclization of γ-arylated valine type derivatives, gained by experimental observations and...

Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Aryl Iodide ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

2020 ◽  
Vol 7 (6) ◽  
pp. 885-889 ◽  
Author(s):  
Xinxin Qi ◽  
Zhi-Peng Bao ◽  
Xiao-Feng Wu
Keyword(s):  
Sulfonyl Chlorides ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

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