Mechanistic Understanding Enables Chemoselective sp3 over sp2 C-H Activation in Pd-Catalyzed Carbonylative Cyclization of Amino Acids
Mechanistic insights into the factors that control chemoselectivity in competing C(sp2)-H and C(sp3)-H activation pathways in the palladium-catalyzed carbonylative cyclization of γ-arylated valine type derivatives, gained by experimental observations and...
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2013 ◽
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