Hydration and Dynamic Behavior of Poly(N-isopropylacrylamide)s in Aqueous Solution:  A Sharp Phase Transition at the Lower Critical Solution Temperature

2006 ◽  
Vol 128 (31) ◽  
pp. 10030-10031 ◽  
Author(s):  
Yousuke Ono ◽  
Toshiyuki Shikata
Keyword(s):  
Phase Transition ◽  
Aqueous Solution ◽  
Dynamic Behavior ◽  
Lower Critical Solution Temperature ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Sharp Phase Transition

Modified Poly (N-Isopropylacrylamide) Hydrogels for Drug Delivery

2010 ◽  
Author(s):  
Guoguang Fu ◽  
Winston Soboyejo
Keyword(s):  
Phase Transition ◽  
Drug Delivery ◽  
Aqueous Solution ◽  
Drug Release ◽  
Lower Critical Solution Temperature ◽  
Environmental Temperature ◽  
Swelling Behavior ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Release Profiles

Thermo-responsive hydrogel can change their swelling behavior and drug release characteristics in response to environmental temperature [1–5]. Poly(N-isopropylacrylamide) (PNIPA) hydrogel undergoes a phase transition when the temperatue is lower than a lower critical solution temperature (LCST) of ∼32°C in aqueous solution [8], and drug release profiles in PNIPA hydrogel can be controlled by the alternation of their solution temperatures.

Synthesis and thermo-responsive behavior of helical polyacetylenes derived from proline

2018 ◽  
Vol 54 (85) ◽  
pp. 12081-12084 ◽  
Author(s):  
Ge Shi ◽  
Sheng Wang ◽  
Xiaoyan Guan ◽  
Jie Zhang ◽  
Xinhua Wan
Keyword(s):  
Phase Transition ◽  
Aqueous Solution ◽  
Lower Critical Solution Temperature ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Responsive Behavior

Structurally simple, biomass-based helical polyacetylene exhibits an unexpected lower critical solution temperature in an aqueous solution with a narrow phase-transition window and a small hysteresis.

A polyelectrolyte-containing copolymer with a gas-switchable lower critical solution temperature-type phase transition

2019 ◽  
Vol 10 (2) ◽  
pp. 260-266 ◽  
Author(s):  
Jin-Jin Li ◽  
Yin-Ning Zhou ◽  
Zheng-Hong Luo ◽  
Shiping Zhu
Keyword(s):  
Phase Transition ◽  
Cloud Point ◽  
Lower Critical Solution Temperature ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Type Phase

A polyelectrolyte-containing copolymer with a CO2/N2-switchable cloud point, resulting from the gas-induced alternation of hydrophilicity, was prepared.

scholarly journals Unexpected LCST-type phase behaviour of a poly(vinyl thiazolium) polymer in acetone

RSC Advances ◽  
2016 ◽  
Vol 6 (62) ◽  
pp. 57117-57121 ◽  
Author(s):  
Konrad Grygiel ◽  
Weiyi Zhang ◽  
Christophe Detrembleur ◽  
Jiayin Yuan
Keyword(s):  
Phase Transition ◽  
Lower Critical Solution Temperature ◽  
Acetone Solution ◽  
Phase Behaviour ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Type Phase

A poly(vinyl thiazolium) polymer in acetone solution exhibited an unexpected lower critical solution temperature (LCST)-type phase transition.

Synthesis and Characterization of Comb-Type Grafted Hydrogels

2012 ◽  
Vol 602-604 ◽  
pp. 1274-1284
Author(s):  
Ping Zhang ◽  
Shi Pu Li ◽  
Xin Yu Wang ◽  
Hong Lian Dai
Keyword(s):  
Aqueous Solution ◽  
Fluorescence Spectroscopy ◽  
Lower Critical Solution Temperature ◽  
Ammonium Persulfate ◽  
Solution Temperature ◽  
Synthesis And Characterization ◽  
Critical Solution Temperature

The grafted hydrogels of N-isopropylacrylamide (IPAAm) with 2-hydroxyethylacrylate (HEA) was prepared in an aqueous solution using ammonium persulfate (APS) and N,N,N’,N’-tetramethylethylene diamine (TEMED) as an accelerator. Lower critical solution temperature (LCST) and swelling ratios were measured as a function of temperature. The properties of the hydrogels contained pyrenyl probe in water were investigated by fluorescence spectroscopy.

Key Factors to Prepare Polyelectrolytes Showing Temperature-Sensitive Lower Critical Solution Temperature-type Phase Transitions in Water

2012 ◽  
Vol 65 (1) ◽  
pp. 91 ◽  
Author(s):  
Yuki Kohno ◽  
Hiroyuki Ohno
Keyword(s):  
Phase Transition ◽  
Lower Critical Solution Temperature ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Phase Behaviour ◽  
Solution Temperature ◽  
Temperature Sensitive ◽  
Key Factors ◽  
Critical Solution Temperature ◽  
Type Phase

Tetrabutylphosphonium styrenesulfonate and its homopolymer showed a lower critical solution temperature-type phase transition in water. As the hydrophobicity of these monomeric and polymeric salts affects phase behaviour, the phase transition temperature of the polyelectrolyte was changed by the introduction of monomers having different alkyl chain length on the phosphonium cations.

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