Diarylurea-Linked Zinc Porphyrin Dimer as a Dual-Mode Artificial Receptor:  Supramolecular Control of Complexation-Facilitated Photoinduced Electron Transfer

2003 ◽  
Vol 125 (14) ◽  
pp. 4068-4069 ◽  
Author(s):  
Shigeyuki Yagi ◽  
Masayuki Ezoe ◽  
Isamu Yonekura ◽  
Toru Takagishi ◽  
Hiroyuki Nakazumi
2010 ◽  
Vol 16 (29) ◽  
pp. 8748-8756 ◽  
Author(s):  
Barbara Ventura ◽  
Lucia Flamigni ◽  
Maryline Beyler ◽  
Valérie Heitz ◽  
Jean-Pierre Sauvage

1999 ◽  
Vol 103 (5) ◽  
pp. 557-559 ◽  
Author(s):  
Denis LeGourriérec ◽  
Mikael Andersson ◽  
Jan Davidsson ◽  
Emad Mukhtar ◽  
Licheng Sun ◽  
...  

2011 ◽  
Vol 24 (11) ◽  
pp. 1101-1109 ◽  
Author(s):  
Fuling Wang ◽  
Jianguo Tang ◽  
Jixian Liu ◽  
Yao Wang ◽  
Rui Wang ◽  
...  

2007 ◽  
Vol 9 (38) ◽  
pp. 5260 ◽  
Author(s):  
David Curiel ◽  
Kei Ohkubo ◽  
Jeffrey R. Reimers ◽  
Shunichi Fukuzumi ◽  
Maxwell J. Crossley

2007 ◽  
Vol 11 (05) ◽  
pp. 368-374 ◽  
Author(s):  
Shunichi Fukuzumi ◽  
Yukiyasu Kashiwagi

A supramolecular ferrocene-zinc porphyrin-pyridylnaphthalenediimide triad is formed by coordinating the pyridine entity of pyridylnaphthalenediimide with the zinc ion of a ferrocene-zinc porphyrin dyad in benzonitrile. The fluorescence of the zinc porphyrin moiety is efficiently quenched by photoinduced electron transfer from the singlet excited state of the zinc porphyrin moiety to the naphthalenediimide moiety. This is followed by subsequent electron transfer from the ferrocene moiety to the zinc porphyrin radical cation to produce the final charge-separated state, ferricenium ion-zinc porphyrin-naphthalenediimide radical anion, which is successfully detected as a transient absorption spectrum in the laser flash photolysis. The decay of the charge-separated state obeys first-order kinetics irrespective of the initial concentration of the charge-separated state to afford a long lifetime (320 μs). This is the first example of a supramolecular triad that has a long lifetime as compared with the charge-separated state lifetime of the component dyad.


Author(s):  
Takashi Hayashi ◽  
Tetsuo Takimura ◽  
Takafumi Ohara ◽  
Yutaka Hitomi ◽  
Hisanobu Ogoshi

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