Design and test of wirelessly powered IPMC artificial muscle for aquatic ecosystem health applications

Aquatic environments and water resources face a variety of risks from numerous sources of pollution. In this paper, we propose a preliminary mechanism for realizing robotic technology practically and cost-effectively for monitoring these pollutions. The presented system is a small robotic fish propelled by a beam of ionic polymer-metal composite (IPMC) artificial muscle that imitates the motion of a small Scorpis Georgiana fish. One of the superiorities of the proposed model is the IPMC actuation mechanism powered by a battery that is charged wirelessly from a solar panel source. This approach enables us to produce a robotic fish that works ceaselessly without being forced to carry the solar panel load. Moreover, we present a method to control the flapping motion of a robotic fish by taking advantage of a tiny Wi-Fi module that yields more working range, bulky data sending, low power consumption, simple programing, and convenient communication for creating a network with other similar robots. All these beneficial characteristics make the proposed structure a promising candidate for detecting pollution on the surface of aquatic environments and sending/recording necessary data in collaboration with desirable sensors. Theoretical considerations support experimental results reported in the paper.

Anomalous Thermal Characteristics of Poly(Ionic Liquids) Derived from 1-Butyl-2,3-dimethyl-4-vinylimidazolium Salts

The synthesis of 1-butyl-2,3-dimethyl-4-vinylimidazolium triflate, its polymerization, and ion exchange to yield a trio of 1-butyl-2,3-dimethyl-4-vinylimidazolium polymers is described. Irrespective of the nature of the anion, substitution at the 2-position of the imidazolium moiety substantially increases the distance between the anion and cation. The methyl substituent at the 2-position also served to expose the importance of H-bonding for the attractive potential between imidazolium moiety and anions in polymers without a methyl group at the 2-position. The thermal characteristics of poly(1-butyl-2,3-dimethyl-4-vinylimidazolium) salts and corresponding poly(1-ethyl-3-methyl-4-vinylimidazolium) salts were evaluated. While the mid-point glass transition temperatures, Tg-mid, for 1-ethyl-3-methyl-4-vinylimidazolium polymers with CF3SO3−, (CF3SO2)2N− and PF6− counterions, were 153 °C, 88 °C and 200 °C, respectively, the Tg-mid values for 1-butyl-2,3-dimethyl-4vinylimidazolium polymers with corresponding counter-ions were tightly clustered at 98 °C, 99 °C and 84 °C, respectively. This dramatically reduced influence of the anion type on the glass transition temperature was attributed to the increased distance between the center of the anions and cations in the 1-butyl-2,3-dimethyl-4-vinylimidazolium polymer set, and minimal H-bonding interactions between the respective anions and the 1-butyl-2,3-dimethyl-4-vinylimidazolium moiety. It is believed that this is the first observation of substantial independence of the glass transition of an ionic polymer on the nature of its counterion.

Approximate field measures for ionic polymer-metal composite Materials and a simplified Order-of-magnitude actuator model

As the field of soft robotics grows and new applications for this technology are discovered, the use of simplified models for the soft actuators found in these devices will be critical. In this study we explore arguments based on the magnitude of field gradients that arise in the ionic polymer-metal composite under large applied voltages and their use for approximating measures of the fields inside the polymer. Using the order-of-magnitude based arguments provides exceptional results for quantifying the field measures of maximum ionic concentration and electric potential within the bulk of the polymer. These measures are leveraged to reconstruct the fields themselves in such a way that the internal bending moments generated inside the actuator may be approximated. With the internal moments, a simplified kinematic model may be used to formulate the steady-state actuator response of the IPMC. This actuator model shows a great deal of accuracy as compared to a full multiphysics model, and we discuss the prospects for future development of this model to account for dynamic actuation.

Performance Enhancement of Ionic Polymer-Metal Composite Actuators with Polyethylene Oxide

Current ionic polymer-metal composite (IPMC) always proves inadequate in terms of large attenuation and short working time in air due to water leakage. To address this problem, a feasible and effective solution was proposed in this study to enhance IPMC performance operating in air by doping polyethylene oxide (PEO) with superior water retention capacity into Nafion membrane. The investigation of physical characteristics of membranes blended with varying PEO contents revealed that PEO/Nafion membrane with 20 wt% PEO exhibited a homogeneous internal structure and a high water uptake ratio. At the same time, influences of PEO contents on electromechanical properties of IPMCs were studied, showing that the IPMCs with 20 wt% PEO presented the largest peak-to-peak displacement, the highest volumetric work density, and prolonged stable working time. It was demonstrated that doping PEO reinforced electromechanical performances and restrained displacement attenuation of the resultant IPMC.