ADDITION OF PHENOLS TO THE ETHYLENIC LINKAGE. II. THE ACTION OF PHENOLS OF ALLYL ALCOHOL, ALLYL ACETATE, VINYL ACETATE AND ALLYL ETHERS

1931 ◽  
Vol 53 (9) ◽  
pp. 3390-3396 ◽  
Author(s):  
Joseph B. Niederl ◽  
Richard A. Smith ◽  
Martin E. McGreal
Keyword(s):  
Vinyl Acetate ◽  
Allyl Alcohol ◽  
Allyl Acetate ◽  
Allyl Ethers

Hydroformylation of unsaturated esters and 2,3-dihydrofuran under solventless conditions at room temperature catalysed by rhodium N-pyrrolyl phosphine catalysts

2019 ◽  
Vol 43 (43) ◽  
pp. 16990-16999 ◽  
Author(s):  
W. Alsalahi ◽  
A. M. Trzeciak
Keyword(s):  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Butyl Acrylate ◽  
Room Temperature ◽  
Allyl Acetate ◽  
Unsaturated Esters

Complexes of the type HRh(CO)L3 (where L is an N-pyrrolyl phosphine, e.g. P(NC4H4)3, Ph(NC4H4)2, or PPh2(NC4H4)) were applied in the hydroformylation of less reactive unsaturated substrates (allyl acetate, butyl acrylate, methyl acrylate, 2,3-dihydrofuran, vinyl acetate).

ChemInform Abstract: ALLYL ACETATE AS A NEW REAGENT FOR THE SYNTHESIS OF ALLYL ETHERS

1980 ◽  
Vol 11 (45) ◽  
Author(s):  
G. A. GAREEV ◽  
A. M. BELOUSOV ◽  
YU. M. BELOUSOV ◽  
N. A. CHERKASHINA
Keyword(s):  
Allyl Acetate ◽  
Allyl Ethers

Radical polymerization of allyl alcohol and allyl acetate

2007 ◽  
Vol 18 (12) ◽  
pp. 953-958 ◽  
Author(s):  
Kokoro Iio ◽  
Kentaro Kobayashi ◽  
Mutsuo Matsunaga
Keyword(s):  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Allyl Acetate

Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcohol

1994 ◽  
Vol 72 (9) ◽  
pp. 1961-1965 ◽  
Author(s):  
Michael T. H. Liu ◽  
Yuri N. Romashin ◽  
T. K. Venkatachalam
Keyword(s):  
Rate Constants ◽  
Allyl Alcohol ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Phenyl Ether ◽  
High Yield ◽  
Allyl Ethers ◽  
Oxonium Ylide ◽  
Allyl Phenyl Ether

When photolysis of arylchlorodiazirines is performed in the presence of either alkyl- or allyl-substituted amines, either N-alkyl- or N-allyl-substituted amines result as the sole high-yield (64-93%) products. Photolysis in the presence of phenylallylamine produces a rearranged product in poor yield (11–15%) whereas the reaction of allyl alcohol with arylchlorocarbene gives exclusively diallyl acetals in high yield (70%). The rate constants for these reactions were obtained by laser flash photolysis. Allyl phenyl ether forms a cyclopropanated product when treated with arylchlorocarbene. The different behaviour of these compounds may be attributed to the nucleophilicity at the nitrogen and oxygen centres of these compounds, when the latter are subjected to the substitutions described above. The formation of a cyclopropanated product when allyl phenyl ether is used differs from the reaction of bis (methoxycarbonyl) carbene with allyl ethers, as reported in the literature. The formation of this cyclopropanated product demonstrates the absence of an oxonium ylide intermediate during the reaction.

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