The inhibition and retardation by certain quinones of the peroxideinduced polymerisation of allyl acetate and vinyl acetate

1947 ◽  
Vol 2 ◽  
pp. 342 ◽  
Author(s):  
Paul D. Bartlett ◽  
George S. Hammond ◽  
Harold Kwart
Keyword(s):  
Vinyl Acetate ◽  
Allyl Acetate

Hydroformylation of unsaturated esters and 2,3-dihydrofuran under solventless conditions at room temperature catalysed by rhodium N-pyrrolyl phosphine catalysts

2019 ◽  
Vol 43 (43) ◽  
pp. 16990-16999 ◽  
Author(s):  
W. Alsalahi ◽  
A. M. Trzeciak
Keyword(s):  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Butyl Acrylate ◽  
Room Temperature ◽  
Allyl Acetate ◽  
Unsaturated Esters

Complexes of the type HRh(CO)L3 (where L is an N-pyrrolyl phosphine, e.g. P(NC4H4)3, Ph(NC4H4)2, or PPh2(NC4H4)) were applied in the hydroformylation of less reactive unsaturated substrates (allyl acetate, butyl acrylate, methyl acrylate, 2,3-dihydrofuran, vinyl acetate).

scholarly journals Tropospheric chemical degradation of vinyl and allyl acetate initiated by Cl atoms under high and low NOx conditions

RSC Advances ◽  
2015 ◽  
Vol 5 (60) ◽  
pp. 48154-48163 ◽  
Author(s):  
María B. Blanco ◽  
Iustinian Bejan ◽  
Ian Barnes ◽  
Peter Wiesen ◽  
Mariano A. Teruel
Keyword(s):  
Vinyl Acetate ◽  
Chemical Degradation ◽  
Allyl Acetate ◽  
Cl Atoms

The products of the reactions of Cl atoms with vinyl acetate (VA) and allyl acetate (AA) have been investigated with and without NOx in a 1080 L chamber using in situ FTIR.

Inhibition of Radical-Initiated Vinyl Acetate Polymerisation by Tobacco Smoke Fractions

1974 ◽  
Vol 7 (5) ◽  
Author(s):  
M.A. Nisbet ◽  
S. Schmeller
Keyword(s):  
Benzoyl Peroxide ◽  
Vinyl Acetate ◽  
Tobacco Smoke ◽  
Boiling Point ◽  
Water Bath ◽  
Measuring Time ◽  
Time Required

AbstractBoth the vapour and particulate phases of tobacco smoke have been shown to retard benzoyI-peroxide-initiated polymerisation of vinyl acetate by interception of the radicals involved in the polymerisation process. The extent of inhibition of polymerisation by test compounds is estimated by measuring time taken for a mixture of monomer and benzoyl peroxide, immersed in a water-bath at 70°C, to reach a spontaneous boil and comparing it with the time required for a similar mixture with added retarder to reach boiling point. Units are expressed as minutes of inhibition per part per million of inhibitor × 10

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