Radical polymerization of allyl alcohol and allyl acetate

2007 ◽  
Vol 18 (12) ◽  
pp. 953-958 ◽  
Author(s):  
Kokoro Iio ◽  
Kentaro Kobayashi ◽  
Mutsuo Matsunaga
Keyword(s):  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Allyl Acetate

Synthesis and Radical Polymerizations of N-Substituted Maleimide Bearing Two Olefinic Groups

2014 ◽  
Vol 1033-1034 ◽  
pp. 619-622
Author(s):  
Hua Jing Gao ◽  
Zhao Hui Jin
Keyword(s):  
Maleic Anhydride ◽  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Optically Active ◽  
Optically Active Polymers ◽  
Allyl Ester ◽  
Radical Polymerizations ◽  
Alcohol Radical

A kind of N-substituted maleimide - having two olefinic bonds with different reactivities, (S)-N-Maleoyl-L-leucine allyl ester ((S)-ALMI), was synthesized from maleic anhydride, L-leucine and allyl alcohol. Radical polymerizations were carried out to obtain optically active polymers using 2,2′-azobisisobutyronitrile. Structures of the monomer and polymers obtained were investigated by NMR measurements. In radical polymerizations, the solvents strongly affect the radical polymerization behaviors of (S)-ALMI.

Studies of Allyl Alcohol Radical Polymerization by PFG-HMQC and HMBC NMR at 750 MHz

2002 ◽  
Vol 35 (7) ◽  
pp. 2602-2607 ◽  
Author(s):  
Sung Joon Oh ◽  
David R. Kinney ◽  
Wei Wang ◽  
Peter L. Rinaldi
Keyword(s):  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Alcohol Radical

scholarly journals Biosynthesis of mercapturic acids from allyl alcohol, allyl esters and acrolein

1973 ◽  
Vol 134 (4) ◽  
pp. 1093-1101 ◽  
Author(s):  
Clive M. Kaye
Keyword(s):  
Subcutaneous Injection ◽  
Allyl Alcohol ◽  
Mercapturic Acids ◽  
Allyl Acetate ◽  
Diallyl Phthalate ◽  
Allyl Esters

1. 3-Hydroxypropylmercapturic acid, i.e. N-acetyl-S-(3-hydroxypropyl)-l-cysteine, was isolated, as its dicyclohexylammonium salt, from the urine of rats after the subcutaneous injection of each of the following compounds: allyl alcohol, allyl formate, allyl propionate, allyl nitrate, acrolein and S-(3-hydroxypropyl)-l-cysteine. 2. Allylmercapturic acid, i.e. N-acetyl-S-allyl-l-cysteine, was isolated from the urine of rats after the subcutaneous injection of each of the following compounds: triallyl phosphate, sodium allyl sulphate and allyl nitrate. The sulphoxide of allylmercapturic acid was detected in the urine excreted by these rats. 3. 3-Hydroxypropylmercapturic acid was identified by g.l.c. as a metabolite of allyl acetate, allyl stearate, allyl benzoate, diallyl phthalate, allyl nitrite, triallyl phosphate and sodium allyl sulphate. 4. S-(3-Hydroxypropyl)-l-cysteine was detected in the bile of a rat dosed with allyl acetate.

scholarly journals A comparative 90-day toxicity study of allyl acetate, allyl alcohol and acrolein

Toxicology ◽  
2008 ◽  
Vol 253 (1-3) ◽  
pp. 79-88 ◽  
Author(s):  
Scott S. Auerbach ◽  
Joel Mahler ◽  
Gregory S. Travlos ◽  
Richard D. Irwin
Keyword(s):  
Allyl Alcohol ◽  
Toxicity Study ◽  
Allyl Acetate
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