Coordination Compounds with Delocalized Ground States. α-Dithiodiketone-Substituted Group VI Metal Carbonyls and Related Compounds

1966 ◽  
Vol 88 (22) ◽  
pp. 5174-5179 ◽  
Author(s):  
G. N. Schrauzer ◽  
V. P. Mayweg ◽  
W. Heinrich
Keyword(s):  
Coordination Compounds ◽  
Ground States ◽  
Metal Carbonyls ◽  
Group Vi ◽  
Related Compounds

Beiträge zur Chemie des Bors, XCIX Borylphosphin-Metallcarbonyle der VI. Nebengruppe /Contributions to the Chemistry of Boron, XCIX Borylphosphine Metal Carbonyls of Group VI Transition Metals

1978 ◽  
Vol 33 (11) ◽  
pp. 1313-1317 ◽  
Author(s):  
Heinrich Nöth ◽  
Siu Ning Sze
Keyword(s):  
Transition Metals ◽  
Coordination Compounds ◽  
Spectroscopic Data ◽  
Metal Carbonyls ◽  
Firm Conclusion ◽  
Group Vi ◽  
Indirect Methods ◽  
Direct And Indirect Methods

Abstract The following new types of coordination compounds were prepared by direct and indirect methods: (CO)5M · PR2-B(NR2), cis(CO)4M · (PR2)2BNR2′, cis-(CO)4M · (PR2BNR2′) and (CO)4MO · (R2P)2B(R2P)2B(PR2)2 · Mo(CO)4 (M = Cr, Mo, W). It was assumed that an increased metal-boron interaction would result in the series (CO5M · R2PBR2′, (CO)4M(R2P)2BR′, (CO)3M(R2P)3B. However, no firm conclusion on this point is possible from the spectroscopic data obtained.

ChemInform Abstract: 1,1,1-TRIS(HYDROXYMETHYL)PROPANEPHOSPHITE DERIVATIVES OF GROUP VI METAL CARBONYLS

1979 ◽  
Vol 10 (17) ◽  
Author(s):  
S. C. TRIPATHI ◽  
S. C. SRIVASTAVA ◽  
D. P. PANDEY ◽  
R. P. CHATURVEDI
Keyword(s):  
Metal Carbonyls ◽  
Group Vi ◽  
Derivatives Of

Studies in polymerization. XIII. The activated initiation of vinyl polymerization by metal carbonyls

1962 ◽  
Vol 268 (1335) ◽  
pp. 553-566 ◽  
Keyword(s):  
Kinetic Mechanism ◽  
Molybdenum Hexacarbonyl ◽  
Metal Carbonyls ◽  
Group Vi ◽  
Radical Intermediates ◽  
Vinyl Polymerization ◽  
Organic Halogen ◽  
Halogen Compounds ◽  
Iodine Compounds ◽  
Reaction Proceeds

It has been found that the hexaearbonyls of group VI metals in the presence of some organic halogen compounds are active initiators of vinyl polymerization. Molybdenum hexacarbonyl is the most active, and halogen compounds containing —CC1 3 , —CBr 3 are generally more effective than those with fewer halogen atoms joined to a single carbon. Fluorine and iodine compounds are inactive. A study has been made of the initiation of the polymerization of methyl methacrylate by the Cr(CO) 6 + CCl 4 system. The polymerization is markedly retarded by carbon monoxide. It is shown that the reaction proceeds through free-radical intermediates, and a kinetic mechanism for initiation is derived (equation (4)) leading to the expression (5) for the rate of chain starting. This quantity may be calculated from (5) with the aid of the numerical values in table 3. Kinetic observations are in satisfactory agreement with this mechanism. The nature of the participating reactions is discussed.

Photolysis of Group VI metal carbonyls, (η6-C6H6)Cr(CO)3, (η5-C5H5)Mn(CO)3, (η5-CH3C5H4)Mn(CO)3 and (η5-C5H5)Re(CO)3 in Nujol at 77 K

1991 ◽  
Vol 419 (1-2) ◽  
pp. 113-126 ◽  
Author(s):  
Thomas E. Bitterwolf ◽  
Kimberly A. Lott ◽  
Antony J. Rest ◽  
Joëlle Mascetti
Keyword(s):  
Metal Carbonyls ◽  
Group Vi

Chemistry of the metal carbonyls. Part XXXV. Bis(dicarbonyl-π-cyclopentadienyliron)bis(iodo)germane and related compounds

1966 ◽  
Vol 0 (0) ◽  
pp. 1130-1133 ◽  
Author(s):  
N. Flitcroft ◽  
D. A. Harbourne ◽  
I. Paul ◽  
P. M. Tucker ◽  
F. G. A. Stone
Keyword(s):  
Metal Carbonyls ◽  
Related Compounds
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