Rate Equation for Adsorption of a Neutral Substance at a Metal-Electrolyte Interface

1962 ◽  
Vol 84 (22) ◽  
pp. 4247-4252 ◽  
Author(s):  
Paul. Delahay ◽  
David M. Mohilner
Keyword(s):  
Rate Equation ◽  
Neutral Substance ◽  
Electrolyte Interface

Prediction of Tread Pattern Wear by an Explicit Finite Element Model3

2007 ◽  
Vol 35 (4) ◽  
pp. 276-299 ◽  
Author(s):  
J. C. Cho ◽  
B. C. Jung
Keyword(s):  
Finite Element ◽  
Wear Rate ◽  
Tangential Stress ◽  
Rate Equation ◽  
Constitutive Equations ◽  
Slip Velocity ◽  
Test Results ◽  
Explicit Finite Element ◽  
Driving Condition ◽  
Driving Conditions

Abstract Tread pattern wear is predicted by using an explicit finite element model (FEM) and compared with the indoor drum test results under a set of actual driving conditions. One pattern is used to determine the wear rate equation, which is composed of slip velocity and tangential stress under a single driving condition. Two other patterns with the same size (225/45ZR17) and profile are used to be simulated and compared with the indoor wear test results under the actual driving conditions. As a study on the rubber wear rate equation, trial wear rates are assumed by several constitutive equations and each trial wear rate is integrated along time to yield the total accumulated wear under a selected single cornering condition. The trial constitutive equations are defined by independently varying each exponent of slip velocity and tangential stress. The integrated results are compared with the indoor test results, and the best matching constitutive equation for wear is selected for the following wear simulation of two other patterns under actual driving conditions. Tens of thousands of driving conditions of a tire are categorized into a small number of simplified conditions by a suggested simplification procedure which considers the driving condition frequency and weighting function. Both of these simplified conditions and the original actual conditions are tested on the indoor drum test machines. The two results can be regarded to be in good agreement if the deviation that exists in the data is mainly due to the difference in the test velocity. Therefore, the simplification procedure is justified. By applying the selected wear rate equation and the simplified driving conditions to the explicit FEM simulation, the simulated wear results for the two patterns show good match with the actual indoor wear results.

Density matrix and rate equation analyses for picosecond pump/probe combustion diagnostics

AIAA Journal ◽  
1999 ◽  
Vol 37 ◽  
pp. 723-731
Author(s):  
Thomas Settersten ◽  
Mark Linne ◽  
James Gord ◽  
Gregory Feichtner
Keyword(s):  
Density Matrix ◽  
Rate Equation ◽  
Pump Probe ◽  
Combustion Diagnostics

A New Adsorption Rate Equation in Batch Systems

2018 ◽  
Author(s):  
yongson hong ◽  
Kye-Ryong Sin ◽  
Jong-Su Pak ◽  
Chol-Min Pak
Keyword(s):  
Experimental Data ◽  
Kinetic Analysis ◽  
Adsorption Kinetics ◽  
Rate Equation ◽  
Kinetic Models ◽  
Adsorption Kinetic ◽  
Adsorption Rate ◽  
Batch Systems ◽  
New View

<p><b>In this paper, the deficiencies and cause of previous adsorption kinetic models were revealed, new adsorption rate equation has been proposed and its validities were verified by kinetic analysis of various experimental data.</b> <b>This work is a new view on the adsorption kinetics rather than a comment on the previous adsorption papers.</b></p>

Photo-Current Enhancement at Cu/p-Cu2O/rGO- Electrolyte Interface

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
S.P.A.U.K. Samarakoon ◽  
C.A.N. Fernando
Keyword(s):  
Diffuse Reflectance ◽  
Electrochemical Cell ◽  
Time Development ◽  
Charge Carriers ◽  
Electrochemical Cells ◽  
Current Action ◽  
Electrolyte Interface ◽  
Reduced Graphene ◽  
Efficient Charge ◽  
Photo Current

A considerable photo-current enhancement was found at the Cu/p-Cu2O/rGO-electrolyte interface in a photo-electrochemical cell with compared to that of Cu/p-Cu2O-electrolyte interface. The reason for the photo-current enhancement may be due to the efficient charge separation process provided at Cu/p-Cu2O/rGO-electrolyte interface. Here rGO (reduced graphene oxide) acts as an electron acceptor for the photo-generated charge carriers as it readily accept electrons from the conduction band of p-Cu2O. rGO was synthesized using electro-phoretic deposition (EPD) technique. Fabricated samples were characterized using diffuse reflectance spectra, photo-current action spectra and the time development of the photocurrent of photo-electrochemical cells.

Mechanism of hydration and isomerisation of 4-ethylidene-2,6-di-tert-butyl-2,5-cyclohexadien-1-one. Kinetics, acid-base catalysis and solvent deuterium isotope effects

1979 ◽  
Vol 44 (1) ◽  
pp. 110-122 ◽  
Author(s):  
Jiří Velek ◽  
Bohumír Koutek ◽  
Milan Souček
Keyword(s):  
Aqueous Medium ◽  
Rate Equation ◽  
Kinetic Data ◽  
Isotope Effects ◽  
Base Catalysis ◽  
Quinone Methide ◽  
Reaction Products ◽  
Acid Base ◽  
Deuterium Isotope Effects ◽  
Hydroxybenzyl Alcohol

Competitive hydration and isomerisation of the quinone methide I at 25 °C in an aqueous medium in the region of pH 2.4-13.0 was studied spectrophotometrically. The only reaction products in the studied range of pH are 4-hydroxybenzyl alcohol (II) and 4-hydroxystyrene (III). The form of the overall rate equation corresponds to a general acid-base catalysis. The mechanism of both reactions for three markedly separated pH regions is discussed on the basis of kinetic data and solvent deuterium effect.

Kinetics of catalytic reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst

1983 ◽  
Vol 48 (11) ◽  
pp. 3202-3208 ◽  
Author(s):  
Zdeněk Musil ◽  
Vladimír Pour
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Oxide ◽  
Rate Equation ◽  
Catalytic Reduction ◽  
Zero Order ◽  
Spectroscopic Measurements ◽  
First Order ◽  
Ir Spectroscopic ◽  
Kinetics Of ◽  
Al2o3 Catalyst

The kinetics of the reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst (8.36 mass % CuO) were determined at temperatures between 413 and 473 K. The reaction was found to be first order in NO and zero order in CO. The observed kinetics are consistent with a rate equation derived from a mechanism proposed on the basis of IR spectroscopic measurements.

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