RATE EQUATION FOR ADSORPTION OF A NEUTRAL SUBSTANCE AT A METAL-ELECTROLYTE INTERFACE1

1962 ◽  
Vol 66 (5) ◽  
pp. 959-960 ◽  
Author(s):  
P. Delahay ◽  
D. M. Mohilner
Keyword(s):  
Rate Equation ◽  
Neutral Substance

Prediction of Tread Pattern Wear by an Explicit Finite Element Model3

2007 ◽  
Vol 35 (4) ◽  
pp. 276-299 ◽  
Author(s):  
J. C. Cho ◽  
B. C. Jung
Keyword(s):  
Finite Element ◽  
Wear Rate ◽  
Tangential Stress ◽  
Rate Equation ◽  
Constitutive Equations ◽  
Slip Velocity ◽  
Test Results ◽  
Explicit Finite Element ◽  
Driving Condition ◽  
Driving Conditions

Abstract Tread pattern wear is predicted by using an explicit finite element model (FEM) and compared with the indoor drum test results under a set of actual driving conditions. One pattern is used to determine the wear rate equation, which is composed of slip velocity and tangential stress under a single driving condition. Two other patterns with the same size (225/45ZR17) and profile are used to be simulated and compared with the indoor wear test results under the actual driving conditions. As a study on the rubber wear rate equation, trial wear rates are assumed by several constitutive equations and each trial wear rate is integrated along time to yield the total accumulated wear under a selected single cornering condition. The trial constitutive equations are defined by independently varying each exponent of slip velocity and tangential stress. The integrated results are compared with the indoor test results, and the best matching constitutive equation for wear is selected for the following wear simulation of two other patterns under actual driving conditions. Tens of thousands of driving conditions of a tire are categorized into a small number of simplified conditions by a suggested simplification procedure which considers the driving condition frequency and weighting function. Both of these simplified conditions and the original actual conditions are tested on the indoor drum test machines. The two results can be regarded to be in good agreement if the deviation that exists in the data is mainly due to the difference in the test velocity. Therefore, the simplification procedure is justified. By applying the selected wear rate equation and the simplified driving conditions to the explicit FEM simulation, the simulated wear results for the two patterns show good match with the actual indoor wear results.

Density matrix and rate equation analyses for picosecond pump/probe combustion diagnostics

AIAA Journal ◽  
1999 ◽  
Vol 37 ◽  
pp. 723-731
Author(s):  
Thomas Settersten ◽  
Mark Linne ◽  
James Gord ◽  
Gregory Feichtner
Keyword(s):  
Density Matrix ◽  
Rate Equation ◽  
Pump Probe ◽  
Combustion Diagnostics

A New Adsorption Rate Equation in Batch Systems

2018 ◽  
Author(s):  
yongson hong ◽  
Kye-Ryong Sin ◽  
Jong-Su Pak ◽  
Chol-Min Pak
Keyword(s):  
Experimental Data ◽  
Kinetic Analysis ◽  
Adsorption Kinetics ◽  
Rate Equation ◽  
Kinetic Models ◽  
Adsorption Kinetic ◽  
Adsorption Rate ◽  
Batch Systems ◽  
New View

<p><b>In this paper, the deficiencies and cause of previous adsorption kinetic models were revealed, new adsorption rate equation has been proposed and its validities were verified by kinetic analysis of various experimental data.</b> <b>This work is a new view on the adsorption kinetics rather than a comment on the previous adsorption papers.</b></p>

Mechanism of hydration and isomerisation of 4-ethylidene-2,6-di-tert-butyl-2,5-cyclohexadien-1-one. Kinetics, acid-base catalysis and solvent deuterium isotope effects

1979 ◽  
Vol 44 (1) ◽  
pp. 110-122 ◽  
Author(s):  
Jiří Velek ◽  
Bohumír Koutek ◽  
Milan Souček
Keyword(s):  
Aqueous Medium ◽  
Rate Equation ◽  
Kinetic Data ◽  
Isotope Effects ◽  
Base Catalysis ◽  
Quinone Methide ◽  
Reaction Products ◽  
Acid Base ◽  
Deuterium Isotope Effects ◽  
Hydroxybenzyl Alcohol

Competitive hydration and isomerisation of the quinone methide I at 25 °C in an aqueous medium in the region of pH 2.4-13.0 was studied spectrophotometrically. The only reaction products in the studied range of pH are 4-hydroxybenzyl alcohol (II) and 4-hydroxystyrene (III). The form of the overall rate equation corresponds to a general acid-base catalysis. The mechanism of both reactions for three markedly separated pH regions is discussed on the basis of kinetic data and solvent deuterium effect.

Kinetics of catalytic reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst

1983 ◽  
Vol 48 (11) ◽  
pp. 3202-3208 ◽  
Author(s):  
Zdeněk Musil ◽  
Vladimír Pour
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Oxide ◽  
Rate Equation ◽  
Catalytic Reduction ◽  
Zero Order ◽  
Spectroscopic Measurements ◽  
First Order ◽  
Ir Spectroscopic ◽  
Kinetics Of ◽  
Al2o3 Catalyst

The kinetics of the reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst (8.36 mass % CuO) were determined at temperatures between 413 and 473 K. The reaction was found to be first order in NO and zero order in CO. The observed kinetics are consistent with a rate equation derived from a mechanism proposed on the basis of IR spectroscopic measurements.

Different modulation schemes for direct and external modulators based on various laser sources

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Hazem M. El-Hageen ◽  
P.G. Kuppusamy ◽  
Aadel M. Alatwi ◽  
M. Sivaram ◽  
Z. Ahamed Yasar ◽  
...  
Keyword(s):  
Rate Equation ◽  
Simulation Software ◽  
Optical Systems ◽  
Laser Source ◽  
Optical Link ◽  
Input And Output ◽  
Modulation Techniques ◽  
Different Types ◽  
Laser Sources ◽  
Modulation Schemes

AbstractDifferent types of laser source modulation techniques have been used in various applications depending on the objective. As optical systems extract the laws and the best solutions from experiments and simulations, the present study uses simulation software with different modulation types so the output signals can be compared. The modulators used are Mach-Zehnder, which is an external modulator, and electro-absorption modulator and laser rate equation modulator, which are direct modulators. All these types have an optical link multimode (MM) fiber with a photodiode in the receiver end that can be modeled. The input and output signals are analyzed using different types of modulations.

PLATELET AGGREGATION DOES NOT CONFORM TO SIMPLE PARTICLE COLLISION THEORY

1987 ◽  
Author(s):  
Moideen P Jamaluddin
Keyword(s):  
Platelet Aggregation ◽  
Rate Equation ◽  
Rate Constants ◽  
Kinetic Scheme ◽  
Order Type ◽  
Second Order ◽  
Particle Collision ◽  
Collision Theory ◽  
Rate Law ◽  
First Order

Platelet aggregation kinetics, according to the particle collision theory, generally assumed to apply, ought to conform to a second order type of rate law. But published data on the time-course of ADP-induced single platelet recruitment into aggregates were found not to do so and to lead to abnormal second order rate constants much larger than even their theoretical upper bounds. The data were, instead, found to fit a first order type of rate law rather well with rate constants in the range of 0.04 - 0.27 s-1. These results were confirmed in our laboratory employing gelfiltered calf platelets. Thus a mechanism much more complex than hithertofore recognized, is operative. The following kinetic scheme was formulated on the basis of information gleaned from the literature.where P is the nonaggregable, discoid platelet, A the agonist, P* an aggregable platelet form with membranous protrusions, and P** another aggregable platelet form with pseudopods. Taking into account the relative magnitudes of the k*s and assuming aggregation to be driven by hydrophobic interaction between complementary surfaces of P* and P** species, a rate equation was derived for aggregation. The kinetic scheme and the rate equation could account for the apparent first order rate law and other empirical observations in the literature.

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