Synthetic transformations of tetraaza macrocyclic metal complexes. Preparation of the corrinoid and other unsaturated ring systems by oxidative dehydrogenation reactions of nickel(II), copper(II), and cobalt(II) macrocycles

1975 ◽  
Vol 97 (12) ◽  
pp. 3359-3366 ◽  
Author(s):  
S. C. Tang ◽  
R. H. Holm
Keyword(s):  
Metal Complexes ◽  
Oxidative Dehydrogenation ◽  
Ring Systems ◽  
Dehydrogenation Reactions ◽  
Synthetic Transformations

A Magnetically Ordered Non-Stoichiometric Zinc Ferrite for the Oxidative Dehydrogenation Reactions.

2001 ◽  
Vol 676 ◽  
Author(s):  
J. A. Toledo ◽  
N. Nava ◽  
X. C. Sun ◽  
X. Bokhimi
Keyword(s):  
Catalytic Activity ◽  
Oxidative Dehydrogenation ◽  
Spinel Structure ◽  
Zinc Ferrite ◽  
Room Temperature ◽  
Annealing Temperature ◽  
Octahedral Sites ◽  
Tetrahedral Sites ◽  
Dehydrogenation Reactions ◽  
Hydrothermal Reduction

ABSTRACTZnFe2O4 nanoparticles were prepared by hydrothermal reduction approach. A considerable amount of α-Fe2O3 was segregated in the as-synthesized sample, which diffused into the tetrahedral and octahedral sites of the ZnFe2O4 spinel structure with increasing the annealing temperature. The introduction of Fe3+ into the tetrahedral positions was observed by Mössbauer spectra. Magnetization measurements showed an unusual ferrimagnetic behavior of the ZnFe2O4 phase, even at room temperature, confirming the introduction of Fe3+ into the tetrahedral sites of the spinel structure. Catalytic activity measured in the oxidative dehydrogenation of 1-butene reaction increased with increasing annealing temperature, indicating that those interactions of Fe3+ in tetrahedral and octahedral positions also promotes the activity and selectivity to butadiene formation.

scholarly journals Boron-doped graphene as a metal-free catalyst for gas-phase oxidation of benzyl alcohol to benzaldehyde

RSC Advances ◽  
2018 ◽  
Vol 8 (20) ◽  
pp. 11222-11229 ◽  
Author(s):  
Wenjun Cheng ◽  
Xueting Liu ◽  
Na Li ◽  
Jiatong Han ◽  
Shuangming Li ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Gas Phase ◽  
Oxidative Dehydrogenation ◽  
Metal Free ◽  
Boron Doped ◽  
Oxidation Of Benzyl Alcohol ◽  
Phase Oxidation ◽  
Doped Graphene ◽  
Gas Phase Oxidation ◽  
Dehydrogenation Reactions

Boron doped graphene for the oxidative dehydrogenation reactions.

scholarly journals Metal Complexes of Oxadiazole Ligands: An Overview

2019 ◽  
Vol 20 (14) ◽  
pp. 3483 ◽  
Author(s):  
Giovanni Salassa ◽  
Alessio Terenzi
Keyword(s):  
Metal Complexes ◽  
Medicinal Chemistry ◽  
Heterocyclic Ring ◽  
Organic Ligands ◽  
Ring Systems ◽  
General Overview ◽  
Research Fields ◽  
Scientific Disciplines ◽  
Synthetic Approaches

Oxadizoles are heterocyclic ring systems that find application in different scientific disciplines, from medicinal chemistry to optoelectronics. Coordination with metals (especially the transition ones) proved to enhance the intrinsic characteristics of these organic ligands and many metal complexes of oxadiazoles showed attractive characteristics for different research fields. In this review, we provide a general overview on different metal complexes and polymers containing oxadiazole moieties, reporting the principal synthetic approaches adopted for their preparation and showing the variety of applications they found in the last 40 years.

scholarly journals Oxygen-Functionalized Few-Layer Graphene Sheets as Active Catalysts for Oxidative Dehydrogenation Reactions

ChemSusChem ◽  
2013 ◽  
Vol 6 (5) ◽  
pp. 732-732
Author(s):  
Viviane Schwartz ◽  
Wujun Fu ◽  
Yu-Tung Tsai ◽  
Harry M. Meyer ◽  
Adam J. Rondinone ◽  
...  
Keyword(s):  
Oxidative Dehydrogenation ◽  
Graphene Sheets ◽  
Layer Graphene ◽  
Dehydrogenation Reactions ◽  
Few Layer Graphene

A study of the effect of cesium loading on the phase transformation of iron in iron phosphate over the oxidative dehydrogenation reactions

2014 ◽  
Vol 231 (1-3) ◽  
pp. 123-129 ◽  
Author(s):  
Faiza B. Khan ◽  
Venkata D. B. C. Dasireddy ◽  
K. Bharuth-Ram ◽  
H. Masenda ◽  
H. B. Friedrich
Keyword(s):  
Phase Transformation ◽  
Oxidative Dehydrogenation ◽  
Iron Phosphate ◽  
Dehydrogenation Reactions
Sign in / Sign up

Export Citation Format

Share Document