Octahedral metal carbonyls. 54. Rates of chelate ring closure in five-coordinate metal carbonyl intermediates

1983 ◽  
Vol 105 (16) ◽  
pp. 5505-5506 ◽  
Author(s):  
Gerard R. Dobson ◽  
Saber E. Mansour ◽  
D. Eric Halverson ◽  
Erika S. Erikson
Keyword(s):  
Chelate Ring ◽  
Metal Carbonyl ◽  
Ring Closure ◽  
Metal Carbonyls

Octahedral metal carbonyls. 77. Kinetics of chelate ring closure via olefin-tungsten bond formation in chlorobenzene solvates of tungsten carbonyl intermediates

1992 ◽  
Vol 31 (16) ◽  
pp. 3482-3488 ◽  
Author(s):  
Shulin Zhang ◽  
I Hsiung Wang ◽  
Paul H. Wermer ◽  
Charles B. Dobson ◽  
Gerard R. Dobson
Keyword(s):  
Chelate Ring ◽  
Bond Formation ◽  
Ring Closure ◽  
Metal Carbonyls ◽  
Tungsten Carbonyl ◽  
Kinetics Of

Mechanism of chelate ring-opening in metal carbonyl complexes

1974 ◽  
Vol 13 (3) ◽  
pp. 627-631 ◽  
Author(s):  
William J. Knebel ◽  
Robert J. Angelici
Keyword(s):  
Ring Opening ◽  
Chelate Ring ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

scholarly journals Übergangsmetall-substituierte VB Elementsysteme, 7.

1975 ◽  
Vol 30 (3-4) ◽  
pp. 229-234 ◽  
Author(s):  
Wolfgang Malisch ◽  
Peter Panster
Keyword(s):  
Transition Metal ◽  
Mass Spectroscopy ◽  
Bond Cleavage ◽  
Metal Carbonyl ◽  
Metal Carbonyls ◽  
H Nmr ◽  
Complex Metal ◽  
Stable Species ◽  
New Compounds

The reaction of SbBr3 with the complex metal carbonyl anions [π-C5H6(CO)3M]Na (M = Mo, W) leads to the formation of transition metal antimony bromides π-C5H5(CO)3M-Sb̅-Br2, which can be further metallated, yielding the stable species [XXX]All bromine substituted transition metal stibines prove to be excellent coordinating ligands and can easily be introduced into activated metal carbonyls. The interaction of π-C5H5(CO)3M-Sb̅Br2, with bromine results in a quantitative Sb-M bond cleavage, presumably via primary formation of pentavalent intermediates. All new compounds are fully characterized by means of IR, 1H NMR and mass spectroscopy.

Sign in / Sign up

Export Citation Format

Share Document