Mechanism of chelate ring-opening in metal carbonyl complexes

1974 ◽  
Vol 13 (3) ◽  
pp. 627-631 ◽  
Author(s):  
William J. Knebel ◽  
Robert J. Angelici
Keyword(s):  
Ring Opening ◽  
Chelate Ring ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

scholarly journals Recent advances in metathesis-derived polymers containing transition metals in the side chain

2015 ◽  
Vol 11 ◽  
pp. 2747-2762 ◽  
Author(s):  
Ileana Dragutan ◽  
Valerian Dragutan ◽  
Bogdan C Simionescu ◽  
Albert Demonceau ◽  
Helmut Fischer
Keyword(s):  
Transition Metal ◽  
Transition Metal Complexes ◽  
Ring Opening ◽  
Metal Carbonyl ◽  
Side Chain ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Modified Polymers ◽  
Recent Advances ◽  
Late Transition

This account critically surveys the field of side-chain transition metal-containing polymers as prepared by controlled living ring-opening metathesis polymerization (ROMP) of the respective metal-incorporating monomers. Ferrocene- and other metallocene-modified polymers, macromolecules including metal-carbonyl complexes, polymers tethering early or late transition metal complexes, etc. are herein discussed. Recent advances in the design and syntheses reported mainly during the last three years are highlighted, with special emphasis on new trends for superior applications of these hybrid materials.

MULTIPLE SCATTERING EFFECTS IN THE COBALT K-EDGE EXAFS OF METAL CARBONYL COMPLEXES

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-589-C8-592
Author(s):  
N. BINSTED ◽  
S. L. COOK ◽  
J. EVANS ◽  
R. J. PRICE ◽  
G. N. GREAVES
Keyword(s):  
Multiple Scattering ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Scattering Effects ◽  
Multiple Scattering Effects

Transition Metal Carbonyl Complexes of an N-Heterocyclic Carbene Stabilized Silyliumylidene Ion

2019 ◽  
Vol 58 (21) ◽  
pp. 14931-14937 ◽  
Author(s):  
Philipp Frisch ◽  
Tibor Szilvási ◽  
Amelie Porzelt ◽  
Shigeyoshi Inoue
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

Polyoxometalate-supported metal carbonyl derivatives: from synthetic strategies to structural diversity and applications

2019 ◽  
Vol 6 (11) ◽  
pp. 3041-3056 ◽  
Author(s):  
Jingkun Lu ◽  
Peipei He ◽  
Jingyang Niu ◽  
Jingping Wang
Keyword(s):  
Catalytic Properties ◽  
Metal Carbonyl ◽  
Structural Diversity ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Carbonyl Derivatives ◽  
Supported Metal

This review aims to give an overview of the POM-supported metal carbonyl complexes obtained so far, focusing on their structural diversity and potential photochemical and catalytic properties.

Selected strategies for improving sensitivity and reliability of immunoassays

1994 ◽  
Vol 40 (3) ◽  
pp. 347-357 ◽  
Author(s):  
L J Kricka
Keyword(s):  
Drugs Of Abuse ◽  
Metal Carbonyl ◽  
Step Test ◽  
Detection Methods ◽  
Carbonyl Complexes ◽  
Assay Sensitivity ◽  
Metal Carbonyl Complexes ◽  
One Step ◽  
Polymerase Chain ◽  
Catalyzed Reporter Deposition

Abstract Selected recent advances in immunoassay are reviewed. Development has continued on new labels (beta-lactamase, pyrophosphatase, luciferases, photoproteins, pyridopyridazines, europium cryptates, metal carbonyl complexes, porphines, phosphors) and label-detection methods (e.g., chemiluminescence assays, thermometric assays, NADP(+)- and FADP-based coupled assays). Various methods have been explored to increase assay sensitivity, including label amplification via catalyzed reporter deposition (peroxidase label) and immuno-polymerase chain reaction (DNA label). The focus of new immunoassay strategies has been on improved reliability (bispecific antibodies), assay simplification (piezoelectric and surface plasmon resonance immunosensors, phase-modulation fluorescence spectroscopy, polymerized bilayer assemblies), and simultaneous multianalyte testing (e.g., quadruple labeling with lanthanides, one-step test devices for drugs of abuse).

Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes

2004 ◽  
Vol 76 (3) ◽  
pp. 557-564 ◽  
Author(s):  
Y. D. Y. L. Getzler ◽  
Viswanath Mahadevan ◽  
E. B. Lobkovsky ◽  
G. W. Coates
Keyword(s):  
Lewis Acid ◽  
Kinetic Resolution ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Enantiomerically Pure ◽  
Metal Carbonyl Complexes ◽  
Pure Complex

The stereochemistry of epoxide carbonylation using bimetallic [Lewis acid]+[Co(CO)4]- complexes is reported. The achiral complex [(salph)Al(THF)2][Co(CO)4] stereospecifically carbonylates cis- and trans-2-butene oxide to the trans- and cis-β-lactones, respectively. Preliminary experiments regarding the carbonylative kinetic resolution of racemic trans-2-butene oxide using the enantiomerically pure complex [(R,R-salcy)Al(THF)2][Co(CO)4] are also reported.

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