Kinetics of the reaction of .beta.-methoxy-.alpha.-nitrostilbene with thiolate ions. First direct observation of the intermediate in a nucleophilic vinylic substitution

Claude F. Bernasconi; Robert B. Killion; Julianne Fassberg; Zvi Rappoport

doi:10.1021/ja00199a068

Kinetics of the reaction of .beta.-methoxy-.alpha.-nitrostilbene with thiolate ions. First direct observation of the intermediate in a nucleophilic vinylic substitution

Journal of the American Chemical Society ◽

10.1021/ja00199a068 ◽

1989 ◽

Vol 111 (17) ◽

pp. 6862-6864 ◽

Cited By ~ 16

Author(s):

Claude F. Bernasconi ◽

Robert B. Killion ◽

Julianne Fassberg ◽

Zvi Rappoport

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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Kinetics of the Reactions of .beta.-Methoxy-.alpha.-nitrostilbene with Methoxyamine and N-Methylmethoxyamine. Direct Observation of the Intermediate in Nucleophilic Vinylic Substitution

Journal of the American Chemical Society ◽

10.1021/ja00111a006 ◽

1995 ◽

Vol 117 (6) ◽

pp. 1703-1711 ◽

Cited By ~ 27

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Irina Eventova ◽

Zvi Rappoport

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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ChemInform Abstract: Kinetics of the Reaction of β-Methoxy-α-nitrostilbene with Thiolate Ions. First Direct Observation of the Intermediate in a Nucleophilic Vinylic Substitution

ChemInform ◽

10.1002/chin.198947069 ◽

1989 ◽

Vol 20 (47) ◽

Author(s):

C. F. BERNASCONI ◽

R. B. JUN. KILLION ◽

J. FASSBERG ◽

Z. RAPPOPORT

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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Kinetics of reactions of amines with .alpha.-nitro-.beta.-substituted-stilbenes in 50% dimethyl sulfoxide-50% water. Search for the intermediate in nucleophilic vinylic substitution reactions

The Journal of Organic Chemistry ◽

10.1021/jo00302a020 ◽

1990 ◽

Vol 55 (15) ◽

pp. 4568-4575 ◽

Cited By ~ 7

Author(s):

Claude F. Bernasconi ◽

Julianne Fassberg ◽

Robert B. Killion ◽

Zvi Rappoport

Keyword(s):

Dimethyl Sulfoxide ◽

Substitution Reactions ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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ChemInform Abstract: Kinetics of Reactions of Thiolate Ions with α-Nitro β-Substituted Stilbenes in 50% Me2SO-50% Water. Observation of the Intermediate in Nucleophilic Vinylic Substitution Reactions.

ChemInform ◽

10.1002/chin.199032085 ◽

1990 ◽

Vol 21 (32) ◽

Author(s):

C. F. BERNASCONI ◽

J. FASSBERG ◽

R. B. JUN. KILLION ◽

Z. RAPPOPORT

Keyword(s):

Substitution Reactions ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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Reaction of N-methylmethoxyamine with .beta.-methoxy-.alpha.-nitrostilbene. First direct observation of the intermediate in a nucleophilic vinylic substitution with an amine nucleophile

Journal of the American Chemical Society ◽

10.1021/ja00069a065 ◽

1993 ◽

Vol 115 (16) ◽

pp. 7513-7514 ◽

Cited By ~ 7

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Zvi Rappoport ◽

Irina Eventova

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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ChemInform Abstract: Kinetics of Reactions of Hydroxide Ion and Water with β-X- Substituted α-Nitrostilbenes (X: Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% Water. Search for the Intermediate in Nucleophilic Vinylic Substitution.

ChemInform ◽

10.1002/chin.199141059 ◽

2010 ◽

Vol 22 (41) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

J. FASSBERG ◽

R. B. JUN. KILLION ◽

D. F. SCHUCK ◽

Z. RAPPOPORT

Keyword(s):

Hydroxide Ion ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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Kinetics of reactions of thiolate ions with .alpha.-nitro .beta.-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions

Journal of the American Chemical Society ◽

10.1021/ja00164a045 ◽

1990 ◽

Vol 112 (8) ◽

pp. 3169-3177 ◽

Cited By ~ 18

Author(s):

Claude F. Bernasconi ◽

Julianne Fassberg ◽

Robert B. Killion ◽

Zvi Rappoport

Keyword(s):

Substitution Reactions ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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Kinetics of reactions of hydroxide ion and water with .beta.-X-substituted .alpha.-nitrostilbenes (X = Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% water. Search for the intermediate in nucleophilic vinylic substitution

Journal of the American Chemical Society ◽

10.1021/ja00013a033 ◽

1991 ◽

Vol 113 (13) ◽

pp. 4937-4946 ◽

Cited By ~ 9

Author(s):

Claude F. Bernasconi ◽

Julianne Fassberg ◽

Robert B. Killion ◽

David F. Schuck ◽

Zvi Rappoport

Keyword(s):

Hydroxide Ion ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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Nucleophilic Vinylic Substitution in Perfluoroacylchromenes. Diastereoselective Synthesis of Push–Pull Enamino Ketones

Russian Journal of Organic Chemistry ◽

10.1134/s1070428021070046 ◽

2021 ◽

Vol 57 (7) ◽

pp. 1053-1062

Author(s):

V. A. Osyanin ◽

K. S. Korzhenko ◽

D. A. Rashchepkina ◽

D. V. Osipov ◽

Yu. N. Klimochkin

Keyword(s):

Diastereoselective Synthesis ◽

Enamino Ketones ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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ChemInform Abstract: Synthesis and Reactivity of 3-Chloro-3-trifluoromethylacroleins: Stabilisation of the Tetrahedral Intermediate in a Nucleophilic Vinylic “Substitution”.

ChemInform ◽

10.1002/chin.199438050 ◽

2010 ◽

Vol 25 (38) ◽

pp. no-no

Author(s):

G. ALVERNHE ◽

D. GREIF ◽

B. LANGLOIS ◽

A. LAURENT ◽

I. LE DREAN ◽

...

Keyword(s):

Tetrahedral Intermediate ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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