Kinetics of reactions of thiolate ions with .alpha.-nitro .beta.-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions

Claude F. Bernasconi; Julianne Fassberg; Robert B. Killion; Zvi Rappoport

doi:10.1021/ja00164a045

Kinetics of reactions of thiolate ions with .alpha.-nitro .beta.-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions

Journal of the American Chemical Society ◽

10.1021/ja00164a045 ◽

1990 ◽

Vol 112 (8) ◽

pp. 3169-3177 ◽

Cited By ~ 18

Author(s):

Claude F. Bernasconi ◽

Julianne Fassberg ◽

Robert B. Killion ◽

Zvi Rappoport

Keyword(s):

Substitution Reactions ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

Download Full-text

Kinetics of reactions of amines with .alpha.-nitro-.beta.-substituted-stilbenes in 50% dimethyl sulfoxide-50% water. Search for the intermediate in nucleophilic vinylic substitution reactions

The Journal of Organic Chemistry ◽

10.1021/jo00302a020 ◽

1990 ◽

Vol 55 (15) ◽

pp. 4568-4575 ◽

Cited By ~ 7

Author(s):

Claude F. Bernasconi ◽

Julianne Fassberg ◽

Robert B. Killion ◽

Zvi Rappoport

Keyword(s):

Dimethyl Sulfoxide ◽

Substitution Reactions ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

Download Full-text

ChemInform Abstract: Kinetics of Reactions of Thiolate Ions with α-Nitro β-Substituted Stilbenes in 50% Me2SO-50% Water. Observation of the Intermediate in Nucleophilic Vinylic Substitution Reactions.

ChemInform ◽

10.1002/chin.199032085 ◽

1990 ◽

Vol 21 (32) ◽

Author(s):

C. F. BERNASCONI ◽

J. FASSBERG ◽

R. B. JUN. KILLION ◽

Z. RAPPOPORT

Keyword(s):

Substitution Reactions ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

Download Full-text

Kinetic Analysis of Elementary Steps in Nucleophilic Vinylic Substitution Reactions of .alpha.-Nitro-.beta.-X-stilbenes (X = OCH2CF3, OCH3, NO2) with Various Nucleophiles. Detection of the Intermediate in the Reaction of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene with HOCH2CH2S- and of .beta.-Methoxy-.alpha.-nitrostilbene with CF3CH2O-

Journal of the American Chemical Society ◽

10.1021/ja00105a017 ◽

1994 ◽

Vol 116 (26) ◽

pp. 11764-11774 ◽

Cited By ~ 8

Author(s):

Claude F. Bernasconi ◽

David F. Schuck ◽

Rodney J. Ketner ◽

Minda Weiss ◽

Zvi Rappoport

Keyword(s):

Kinetic Analysis ◽

Substitution Reactions ◽

Elementary Steps ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Halogenophilic and classical Ad N E mechanisms in nucleophilic vinylic substitution reactions involving the anions of transition metal carbonyls

Theoretical and Experimental Chemistry ◽

10.1007/s11237-011-9165-2 ◽

2011 ◽

Vol 46 (6) ◽

pp. 350-358 ◽

Cited By ~ 5

Author(s):

P. K. Sazonov ◽

G. A. Artamkina ◽

I. P. Beletskaya

Keyword(s):

Transition Metal ◽

Metal Carbonyls ◽

Substitution Reactions ◽

Transition Metal Carbonyls ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Kinetics of the Reactions of .beta.-Methoxy-.alpha.-nitrostilbene with Methoxyamine and N-Methylmethoxyamine. Direct Observation of the Intermediate in Nucleophilic Vinylic Substitution

Journal of the American Chemical Society ◽

10.1021/ja00111a006 ◽

1995 ◽

Vol 117 (6) ◽

pp. 1703-1711 ◽

Cited By ~ 27

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Irina Eventova ◽

Zvi Rappoport

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

Download Full-text

Kinetics of the reaction of .beta.-methoxy-.alpha.-nitrostilbene with thiolate ions. First direct observation of the intermediate in a nucleophilic vinylic substitution

Journal of the American Chemical Society ◽

10.1021/ja00199a068 ◽

1989 ◽

Vol 111 (17) ◽

pp. 6862-6864 ◽

Cited By ~ 16

Author(s):

Claude F. Bernasconi ◽

Robert B. Killion ◽

Julianne Fassberg ◽

Zvi Rappoport

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

Download Full-text

ChemInform Abstract: Kinetics of the Reaction of β-Methoxy-α-nitrostilbene with Thiolate Ions. First Direct Observation of the Intermediate in a Nucleophilic Vinylic Substitution

ChemInform ◽

10.1002/chin.198947069 ◽

1989 ◽

Vol 20 (47) ◽

Author(s):

C. F. BERNASCONI ◽

R. B. JUN. KILLION ◽

J. FASSBERG ◽

Z. RAPPOPORT

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

Download Full-text

ChemInform Abstract: Nucleophilic Vinylic Substitution Reactions. Part 2. Reaction of the ( Cyclopentadienyl)dicarbonyliron Anion with β-Halogeno-α,. beta.-difluorostyrenes. Influence of Ionic Association.

ChemInform ◽

10.1002/chin.199719194 ◽

2010 ◽

Vol 28 (19) ◽

pp. no-no

Author(s):

G. A. ARTAMKINA ◽

M. M. SHTERN ◽

P. K. SAZONOV ◽

I. P. BELETSKAYA

Keyword(s):

Ionic Association ◽

Substitution Reactions ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

ChemInform Abstract: Kinetics of Reactions of Hydroxide Ion and Water with β-X- Substituted α-Nitrostilbenes (X: Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% Water. Search for the Intermediate in Nucleophilic Vinylic Substitution.

ChemInform ◽

10.1002/chin.199141059 ◽

2010 ◽

Vol 22 (41) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

J. FASSBERG ◽

R. B. JUN. KILLION ◽

D. F. SCHUCK ◽

Z. RAPPOPORT

Keyword(s):

Hydroxide Ion ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

Download Full-text

ChemInform Abstract: Nucleophilic Vinylic Substitution Reactions. Part 4. Influence of Lithium Cation in the Reaction of Cyclopentadienyldicarbonyliron and 9-Methylfluorene Anions with β-Halogeno-α,β-difluorostyrenes.

ChemInform ◽

10.1002/chin.199917045 ◽

2010 ◽

Vol 30 (17) ◽

pp. no-no

Author(s):

P. K. Sazonov ◽

M. M. Shtern ◽

G. A. Artamkina ◽

I. P. Beletskaya

Keyword(s):

Lithium Cation ◽

Substitution Reactions ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text