Reaction of N-methylmethoxyamine with .beta.-methoxy-.alpha.-nitrostilbene. First direct observation of the intermediate in a nucleophilic vinylic substitution with an amine nucleophile

Claude F. Bernasconi; Aquiles E. Leyes; Zvi Rappoport; Irina Eventova

doi:10.1021/ja00069a065

Reaction of N-methylmethoxyamine with .beta.-methoxy-.alpha.-nitrostilbene. First direct observation of the intermediate in a nucleophilic vinylic substitution with an amine nucleophile

Journal of the American Chemical Society ◽

10.1021/ja00069a065 ◽

1993 ◽

Vol 115 (16) ◽

pp. 7513-7514 ◽

Cited By ~ 7

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Zvi Rappoport ◽

Irina Eventova

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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Kinetics of the Reactions of .beta.-Methoxy-.alpha.-nitrostilbene with Methoxyamine and N-Methylmethoxyamine. Direct Observation of the Intermediate in Nucleophilic Vinylic Substitution

Journal of the American Chemical Society ◽

10.1021/ja00111a006 ◽

1995 ◽

Vol 117 (6) ◽

pp. 1703-1711 ◽

Cited By ~ 27

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Irina Eventova ◽

Zvi Rappoport

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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Kinetics of the reaction of .beta.-methoxy-.alpha.-nitrostilbene with thiolate ions. First direct observation of the intermediate in a nucleophilic vinylic substitution

Journal of the American Chemical Society ◽

10.1021/ja00199a068 ◽

1989 ◽

Vol 111 (17) ◽

pp. 6862-6864 ◽

Cited By ~ 16

Author(s):

Claude F. Bernasconi ◽

Robert B. Killion ◽

Julianne Fassberg ◽

Zvi Rappoport

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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ChemInform Abstract: Kinetics of the Reaction of β-Methoxy-α-nitrostilbene with Thiolate Ions. First Direct Observation of the Intermediate in a Nucleophilic Vinylic Substitution

ChemInform ◽

10.1002/chin.198947069 ◽

1989 ◽

Vol 20 (47) ◽

Author(s):

C. F. BERNASCONI ◽

R. B. JUN. KILLION ◽

J. FASSBERG ◽

Z. RAPPOPORT

Keyword(s):

Direct Observation ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution ◽

Kinetics Of

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Nucleophilic Vinylic Substitution in Perfluoroacylchromenes. Diastereoselective Synthesis of Push–Pull Enamino Ketones

Russian Journal of Organic Chemistry ◽

10.1134/s1070428021070046 ◽

2021 ◽

Vol 57 (7) ◽

pp. 1053-1062

Author(s):

V. A. Osyanin ◽

K. S. Korzhenko ◽

D. A. Rashchepkina ◽

D. V. Osipov ◽

Yu. N. Klimochkin

Keyword(s):

Diastereoselective Synthesis ◽

Enamino Ketones ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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ChemInform Abstract: Synthesis and Reactivity of 3-Chloro-3-trifluoromethylacroleins: Stabilisation of the Tetrahedral Intermediate in a Nucleophilic Vinylic “Substitution”.

ChemInform ◽

10.1002/chin.199438050 ◽

2010 ◽

Vol 25 (38) ◽

pp. no-no

Author(s):

G. ALVERNHE ◽

D. GREIF ◽

B. LANGLOIS ◽

A. LAURENT ◽

I. LE DREAN ◽

...

Keyword(s):

Tetrahedral Intermediate ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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Organocatalytic Enantioselective Nucleophilic Vinylic Substitution by α-Substituted-α-Cyanoacetates under Phase-Transfer Conditions

The Journal of Organic Chemistry ◽

10.1021/jo070024p ◽

2007 ◽

Vol 72 (8) ◽

pp. 3053-3056 ◽

Cited By ~ 30

Author(s):

Mark Bell ◽

Thomas B. Poulsen ◽

Karl Anker Jørgensen

Keyword(s):

Phase Transfer ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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Kinetic Analysis of Elementary Steps in Nucleophilic Vinylic Substitution Reactions of .alpha.-Nitro-.beta.-X-stilbenes (X = OCH2CF3, OCH3, NO2) with Various Nucleophiles. Detection of the Intermediate in the Reaction of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene with HOCH2CH2S- and of .beta.-Methoxy-.alpha.-nitrostilbene with CF3CH2O-

Journal of the American Chemical Society ◽

10.1021/ja00105a017 ◽

1994 ◽

Vol 116 (26) ◽

pp. 11764-11774 ◽

Cited By ~ 8

Author(s):

Claude F. Bernasconi ◽

David F. Schuck ◽

Rodney J. Ketner ◽

Minda Weiss ◽

Zvi Rappoport

Keyword(s):

Kinetic Analysis ◽

Substitution Reactions ◽

Elementary Steps ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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Nucleophilic vinylic substitution. I. Synthesis and reactions of 2-substituted 3,3-dichloroacrylonitriles

The Journal of Organic Chemistry ◽

10.1021/jo00821a026 ◽

1971 ◽

Vol 36 (22) ◽

pp. 3386-3391 ◽

Cited By ~ 12

Author(s):

Robert L. Soulen ◽

David B. Clifford ◽

F. Fleming Crim ◽

Joann A. Johnston

Keyword(s):

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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Nucleophilic vinylic substitution. A single- or a multi-step process?

Accounts of Chemical Research ◽

10.1021/ar00061a002 ◽

1981 ◽

Vol 14 (1) ◽

pp. 7-15 ◽

Cited By ~ 116

Author(s):

Zvi Rappoport

Keyword(s):

Step Process ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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Organocatalytic Enantioselective Nucleophilic Vinylic Substitution by α-Substituted-α-cyanoacetates under Phase-Transfer Conditions.

ChemInform ◽

10.1002/chin.200735092 ◽

2007 ◽

Vol 38 (35) ◽

Author(s):

Mark Bell ◽

Thomas B. Poulsen ◽

Karl Anker Joergensen

Keyword(s):

Phase Transfer ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

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