Asymmetric synthesis of lactones with high enantioselectivity by intramolecular carbon-hydrogen insertion reactions of alkyl diazoacetates catalyzed by chiral rhodium(II) carboxamides

1991 ◽  
Vol 113 (23) ◽  
pp. 8982-8984 ◽  
Author(s):  
Michael P. Doyle ◽  
Arjan Van Oeveren ◽  
Larry J. Westrum ◽  
Marina N. Protopopova ◽  
Thomas W. Clayton
Keyword(s):  
Asymmetric Synthesis ◽  
Insertion Reactions ◽  
Hydrogen Insertion

ChemInform Abstract: Electronic and Steric Control in Carbon-Hydrogen Insertion Reactions of Diazoacetoacetates Catalyzed by Dirhodium(II) Carboxylates and Carboxamides.

ChemInform ◽  
2010 ◽  
Vol 24 (24) ◽  
pp. no-no
Author(s):  
M. P. DOYLE ◽  
L. J. WESTRUM ◽  
W. N. E. WOLTHUIS ◽  
M. M. SEE ◽  
W. P. BOONE ◽  
...  
Keyword(s):  
Insertion Reactions ◽  
Hydrogen Insertion ◽  
Steric Control

scholarly journals Organocatalytic Asymmetric Synthesis of α-Amino Esters from Sulfoxonium Ylides

2021 ◽  
Author(s):  
Wengang Guo ◽  
Hai Huang ◽  
Jianwei Sun
Keyword(s):  
Asymmetric Synthesis ◽  
Insertion Reaction ◽  
Metal Catalyst ◽  
Insertion Reactions ◽  
Amino Esters ◽  
Carbene Insertion

Described here is the first organocatalytic asymmetric N−H insertion reaction of α-carbonyl sulfoxonium ylides. Without a metal catalyst, this reaction represents an attractive complement to the well-established carbene insertion reactions....

Diastereocontrol for Highly Enantioselective Carbon-Hydrogen Insertion Reactions of Cycloalkyl Diazoacetates

1994 ◽  
Vol 116 (10) ◽  
pp. 4507-4508 ◽  
Author(s):  
Michael P. Doyle ◽  
Alexey B. Dyatkin ◽  
Gregory H. P. Roos ◽  
Fina Canas ◽  
Deborah A. Pierson ◽  
...  
Keyword(s):  
Insertion Reactions ◽  
Hydrogen Insertion
Sign in / Sign up

Export Citation Format

Share Document