High Selectivity from Configurational Match/Mismatch in Carbon−Hydrogen Insertion Reactions of Steroidal Diazoacetates Catalyzed by Chiral Dirhodium(II) Carboxamidates

2001 ◽  
Vol 66 (24) ◽  
pp. 8112-8119 ◽  
Author(s):  
Michael P. Doyle ◽  
Simon B. Davies ◽  
Eric J. May
Keyword(s):  
High Selectivity ◽  
Insertion Reactions ◽  
Hydrogen Insertion

ChemInform Abstract: Electronic and Steric Control in Carbon-Hydrogen Insertion Reactions of Diazoacetoacetates Catalyzed by Dirhodium(II) Carboxylates and Carboxamides.

ChemInform ◽  
2010 ◽  
Vol 24 (24) ◽  
pp. no-no
Author(s):  
M. P. DOYLE ◽  
L. J. WESTRUM ◽  
W. N. E. WOLTHUIS ◽  
M. M. SEE ◽  
W. P. BOONE ◽  
...  
Keyword(s):  
Insertion Reactions ◽  
Hydrogen Insertion ◽  
Steric Control

Diastereocontrol for Highly Enantioselective Carbon-Hydrogen Insertion Reactions of Cycloalkyl Diazoacetates

1994 ◽  
Vol 116 (10) ◽  
pp. 4507-4508 ◽  
Author(s):  
Michael P. Doyle ◽  
Alexey B. Dyatkin ◽  
Gregory H. P. Roos ◽  
Fina Canas ◽  
Deborah A. Pierson ◽  
...  
Keyword(s):  
Insertion Reactions ◽  
Hydrogen Insertion
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