Reactions in micelles of cetyltrimethylammonium hydroxide. Test of the pseudophase model for kinetics

1981 ◽  
Vol 85 (26) ◽  
pp. 4118-4125 ◽  
Author(s):  
Clifford A. Bunton ◽  
Leong Huat Gan ◽  
John R. Moffatt ◽  
Laurence S. Romsted ◽  
Gianfranco Savelli
Keyword(s):  
Pseudophase Model

The pseudophase model for microemulsions: Phase diagrams in pseudo-phase space

1984 ◽  
Vol 102 (2) ◽  
pp. 361-369 ◽  
Author(s):  
J Biais ◽  
M Barthe ◽  
B Clin ◽  
P Lalanne
Keyword(s):  
Phase Space ◽  
Phase Diagrams ◽  
Pseudophase Model

Fluorescence quenching of 1-pyrene-carboxaldehyde by iodide ions in the presence of anionic (SDS) and cationic (CTAC) micelles: a quantitative treatment

RSC Advances ◽  
2015 ◽  
Vol 5 (58) ◽  
pp. 46485-46492 ◽  
Author(s):  
Eva Bernal ◽  
José Antonio Lebron ◽  
Beatriz Sarrion ◽  
Pilar Lopez-Cornejo ◽  
Carmen Carmona ◽  
...  
Keyword(s):  
Fluorescence Quenching ◽  
Equilibrium Condition ◽  
Photochemical Reactions ◽  
Iodide Ions ◽  
Pseudophase Model ◽  
Quantitative Treatment

Applicability of the pseudophase model to photochemical reactions in the presence of receptors (micelles) in spite of the fact that the equilibrium condition between free and bound reactants does not hold.

Tests of the pseudophase model of micellar catalysis: its partial failure

1979 ◽  
Vol 101 (5) ◽  
pp. 1253-1259 ◽  
Author(s):  
Clifford A. Bunton ◽  
Laurence S. Romsted ◽  
Gianfranco Savelli
Keyword(s):  
Micellar Catalysis ◽  
Partial Failure ◽  
Pseudophase Model

scholarly journals Effect of Micellar Aggregate on the Kinetics and Mechanism of the Reaction between Ethylene Glycol and Periodate

2014 ◽  
Vol 2014 ◽  
pp. 1-3
Author(s):  
Olaseni Segun Esan
Keyword(s):  
Ethylene Glycol ◽  
Cetyltrimethylammonium Bromide ◽  
Reaction Rate ◽  
The Other ◽  
Bulk Solution ◽  
Kinetic Behavior ◽  
Pseudophase Model ◽  
Micellar Aggregates ◽  
Vis Spectroscopy ◽  
Mechanism Of The Reaction

The oxidation of ethylene glycol by periodate (IO4-) was studied in different micellar aggregates of cetyltrimethylammonium bromide (CTABr) and dodecylamine (DA) by means of UV/Vis spectroscopy. The observed constant Ko was obtained by monitoring the disappearing of ethylene glycol with time at a suitable wavelength under pseudofirst condition. Addition of CTABr and DA inhibits the reaction rate while the kinetic behavior was explained on the association of one of the reactants with the micelles leaving the other reactant in the bulk solution (pseudophase model).

Additions and Corrections: Reactions in Micelles of Cetyltrimethylammonium Hydroxide. Test of the Pseudophase Model for Kinetics.

1982 ◽  
Vol 86 (23) ◽  
pp. 4652-4652
Author(s):  
Clifford Bunton ◽  
Leong-Huat Gan ◽  
John Moffatt ◽  
Laurence Romsted ◽  
Gianfranco Savelli
Keyword(s):  
Pseudophase Model

scholarly journals Humic Acids Aggregates as Microheterogeneus Reaction Media: Alkaline Hydrolysis Reactions

2021 ◽  
Author(s):  
Antonio Cid ◽  
L. García-Río ◽  
Juan C. Mejuto ◽  
A. Saavedra
Keyword(s):  
Humic Acids ◽  
Chemical Stability ◽  
Alkaline Hydrolysis ◽  
Water Solution ◽  
Kinetic Behavior ◽  
Pseudophase Model ◽  
Reaction Media ◽  
Hydrolysis Reactions

The influence of humic aggregates in water solution upon the chemical stability under basic conditions of different substrates has been reviewed. The kinetic behavior of each substrate has been modelized in terms of micellar pseudophase model.

Sign in / Sign up

Export Citation Format

Share Document