The Nature of the van der Waals Interaction of Gases and Solids. I. Second Order Interaction

1958 ◽  
Vol 62 (6) ◽  
pp. 723-728 ◽  
Author(s):  
Mark P. Freeman
Keyword(s):  
Van Der Waals ◽  
Second Order ◽  
Van Der Waals Interaction ◽  
Order Interaction

scholarly journals Investigation of the reaction mechanism of [4 + 2] cyclization of 2,3 dimethylbuta-1,3-diene to methylacrylate using the Michaelis-Menten equation

2018 ◽  
Vol 6 (1) ◽  
pp. 74-81
Author(s):  
Irina Kostiv
Keyword(s):  
Reaction Mechanism ◽  
Molecular Complex ◽  
Rate Constants ◽  
Van Der Waals ◽  
Cycloaddition Reaction ◽  
Effective Rate ◽  
Second Order ◽  
Van Der Waals Interaction ◽  
Reaction Proceeds ◽  
Limiting Stage

The cycloaddition reaction between 2,3‑dimethylbuta-1,3-diene and methylacrylate proceeds by the second order kinetics. The rate constants increase with the increase in the excess of one of the reactants. The change in the effective rate constants is described by the Michaelis–Menten equation indicating that the reaction proceeds through the initial equilibrium stage of formation of a molecular complex stabilized by van der Waals interaction which then transforms into the product. The limiting stage of the reaction is established and its mechanism is suggested.

Effect of media overcoat on van der Waals interaction at the head–disk interface

2005 ◽  
Vol 97 (12) ◽  
pp. 126106 ◽  
Author(s):  
Raymond R. Dagastine ◽  
Lee R. White ◽  
Paul M. Jones ◽  
Yiao-Tee Hsia
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Interaction ◽  
Head Disk Interface ◽  
Disk Interface

scholarly journals Modification of the van der Waals interaction at the Bi2Te3 and Ge(111) interface

2021 ◽  
Vol 5 (2) ◽  
Author(s):  
Kenji Nawa ◽  
Demie Kepaptsoglou ◽  
Arsham Ghasemi ◽  
Philip Hasnip ◽  
Guillermo Bárcena-González ◽  
...  
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Interaction

Separation-dependence evolution of inter-particle interaction in the oriented-attachment growth of nanorods: a case of hexagonal nanocrystals

The Analyst ◽  
2014 ◽  
Vol 139 (13) ◽  
pp. 3393-3397 ◽  
Author(s):  
Yuanqiang Song ◽  
Aifang Liu ◽  
Yu Pan ◽  
Xiaoning Wang ◽  
Jiarui Hu ◽  
...  
Keyword(s):  
Van Der Waals ◽  
Particle Interaction ◽  
Van Der Waals Interaction ◽  
Oriented Attachment ◽  
Coulombic Interaction ◽  
Hexagonal Nanorods

By focusing on hexagonal nanorods, the countering effects of van der Waals interaction and Coulombic interaction on the oriented attachment growth of 1D nanocrystals are investigated.

Sign in / Sign up

Export Citation Format

Share Document