Pressure dependence of carbon trioxide formation in the gas-phase reaction of O(1D) with carbon dioxide

1970 ◽  
Vol 74 (13) ◽  
pp. 2621-2625 ◽  
Author(s):  
William B. DeMore ◽  
C. Dede
Keyword(s):  
Carbon Dioxide ◽  
Gas Phase ◽  
Pressure Dependence ◽  
Phase Reaction ◽  
Gas Phase Reaction

A Gas-Phase Reaction as a Functional Model for the Activation of Carbon Dioxide by Carbonic Anhydrase

2003 ◽  
Vol 42 (41) ◽  
pp. 5087-5090 ◽  
Author(s):  
Detlef Schröder ◽  
Helmut Schwarz ◽  
Stephan Schenk ◽  
Ernst Anders
Keyword(s):  
Carbon Dioxide ◽  
Carbonic Anhydrase ◽  
Gas Phase ◽  
Functional Model ◽  
Phase Reaction ◽  
Gas Phase Reaction

Rate coefficients for the gas-phase reaction of OH radicals with dimethyl sulfide: temperature and O2partial pressure dependence

2006 ◽  
Vol 8 (6) ◽  
pp. 728-736 ◽  
Author(s):  
Mihaela Albu ◽  
Ian Barnes ◽  
Karl H. Becker ◽  
Iulia Patroescu-Klotz ◽  
Raluca Mocanu ◽  
...  
Keyword(s):  
Gas Phase ◽  
Pressure Dependence ◽  
Dimethyl Sulfide ◽  
Rate Coefficients ◽  
Oh Radicals ◽  
Phase Reaction ◽  
Gas Phase Reaction

Gas-phase reaction of chlorine atoms with acrylonitrile. Temperature and pressure dependence

2003 ◽  
Vol 377 (5-6) ◽  
pp. 571-576 ◽  
Author(s):  
Alfonso Aranda ◽  
Yolanda Dı́az de Mera ◽  
Diana Rodrı́guez ◽  
Ana Rodrı́guez ◽  
Beatriz Cabañas ◽  
...  
Keyword(s):  
Gas Phase ◽  
Pressure Dependence ◽  
Phase Reaction ◽  
Chlorine Atoms ◽  
Gas Phase Reaction ◽  
Temperature And Pressure

Gas-phase reactivity of CH3C(O) CH3 with OH radicals at interstellar Temperatures (T = 11.7 – 64.4 K) using the CRESU technique

2019 ◽  
Vol 15 (S350) ◽  
pp. 379-381
Author(s):  
Sergio Blázquez ◽  
Antonio J. Ocaña ◽  
Alberto García ◽  
Bernabé Ballesteros ◽  
André Canosa ◽  
...  
Keyword(s):  
Supersonic Flow ◽  
Low Temperature ◽  
Gas Phase ◽  
Pressure Dependence ◽  
Freezing Point ◽  
Rate Coefficients ◽  
Oh Radicals ◽  
Phase Reaction ◽  
Gas Condensation ◽  
Gas Phase Reaction

AbstractThe rate coefficients, k(T= 11.7 – 64.4 K), for the gas-phase reaction between OH radicals and acetone, CH3C(O) CH3, have been measured using the pulsed CRESU (French acronym for Reaction Kinetics in a Uniform Supersonic Flow) technique, the most suitable one to cool down gases below the freezing point without gas condensation. The experimental k(T) was found to increase as temperature was lowered and is several orders of magnitude higher for low temperature than k(300 K). No pressure dependence of k(20 K) and k(64 K) was observed, while k(50 K) at the largest gas density is twice higher than the average values found at lower gas densities. The obtained values of k(11.7 K) and k(21.1 K) were 2.45’10-10 and 1.39’10-10 cm3 molecule-1 s-1, respectively.

Pressure Dependence of Gas-Phase Reaction Rates

2004 ◽  
Vol 81 (6) ◽  
pp. 832 ◽  
Author(s):  
Stéphanie de Persis ◽  
Alain Dollet ◽  
Francis Teyssandier
Keyword(s):  
Gas Phase ◽  
Pressure Dependence ◽  
Reaction Rates ◽  
Phase Reaction ◽  
Gas Phase Reaction

Prediction of Alkanolamine pKa Values by Combined Molecular Dynamics Free Energy Simulations and ab initio Calculations

2019 ◽  
Author(s):  
Javad Noroozi ◽  
William Smith
Keyword(s):  
Molecular Dynamics ◽  
Free Energy ◽  
Ab Initio Calculations ◽  
Gas Phase ◽  
Quantum Chemical ◽  
Phase Reaction ◽  
Pka Values ◽  
Gas Phase Reaction ◽  
Reaction Free Energy ◽  
Energy Simulations

We use molecular dynamics free energy simulations in conjunction with quantum chemical calculations of gas phase reaction free energy to predict alkanolamines pka values. <br>

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