Gas-phase reaction of Cl with dimethyl sulfide: Temperature and oxygen partial pressure dependence of the rate coefficient

2004 ◽  
Vol 37 (2) ◽  
pp. 66-73 ◽  
Author(s):  
C. Arsene ◽  
I. Barnes ◽  
K. H. Becker ◽  
Th. Benter
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Gas Phase ◽  
Pressure Dependence ◽  
Dimethyl Sulfide ◽  
Rate Coefficient ◽  
Phase Reaction ◽  
Gas Phase Reaction

Rate coefficients for the gas-phase reaction of OH radicals with dimethyl sulfide: temperature and O2partial pressure dependence

2006 ◽  
Vol 8 (6) ◽  
pp. 728-736 ◽  
Author(s):  
Mihaela Albu ◽  
Ian Barnes ◽  
Karl H. Becker ◽  
Iulia Patroescu-Klotz ◽  
Raluca Mocanu ◽  
...  
Keyword(s):  
Gas Phase ◽  
Pressure Dependence ◽  
Dimethyl Sulfide ◽  
Rate Coefficients ◽  
Oh Radicals ◽  
Phase Reaction ◽  
Gas Phase Reaction

scholarly journals Influence of Water on the Gas-Phase Reaction of Dimethyl Sulfide with BrO in the Marine Boundary Layer

ACS Omega ◽  
2021 ◽  
Vol 6 (3) ◽  
pp. 2410-2419
Author(s):  
Junyao Li ◽  
Narcisse T. Tsona ◽  
Shanshan Tang ◽  
Xiuhui Zhang ◽  
Lin Du
Keyword(s):  
Boundary Layer ◽  
Gas Phase ◽  
Dimethyl Sulfide ◽  
Marine Boundary Layer ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Influence Of Water

scholarly journals Pressure dependent low temperature kinetics for CN + CH3CN: competition between chemical reaction and van der Waals complex formation

2016 ◽  
Vol 18 (22) ◽  
pp. 15118-15132 ◽  
Author(s):  
Chantal Sleiman ◽  
Sergio González ◽  
Stephen J. Klippenstein ◽  
Dahbia Talbi ◽  
Gisèle El Dib ◽  
...  
Keyword(s):  
Low Temperature ◽  
Complex Formation ◽  
Gas Phase ◽  
Rate Coefficient ◽  
Flow Reactor ◽  
Slow Flow ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Low Temperature Kinetics ◽  
Temperature And Pressure

The gas phase reaction between the CN radical and acetonitrile CH3CN was investigated experimentally with a CRESU apparatus and a slow flow reactor as well as theoretically to explore the temperature and pressure dependence of its rate coefficient from 354 K down to 23 K.

Gas-phase reaction of (E)-β-farnesene with ozone: Rate coefficient and carbonyl products

2009 ◽  
Vol 43 (20) ◽  
pp. 3182-3190 ◽  
Author(s):  
Ivan Kourtchev ◽  
Iustinian Bejan ◽  
John R. Sodeau ◽  
John C. Wenger
Keyword(s):  
Gas Phase ◽  
Rate Coefficient ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Carbonyl Products

Reaction of O(3P) Atoms with Benzene

2004 ◽  
Vol 218 (4) ◽  
pp. 391-404 ◽  
Author(s):  
Torsten Berndt ◽  
Olaf Böge
Keyword(s):  
Gas Phase ◽  
Pressure Range ◽  
Rate Coefficient ◽  
Flow System ◽  
Product Formation ◽  
Phase Reaction ◽  
Experimental Conditions ◽  
Consecutive Reaction ◽  
Gas Phase Reaction ◽  
Benzene Oxide

AbstractThe gas-phase reaction of O(3P) atoms with benzene was investigated in a flow system in the pressure range of 50–100mbar and a temperature of 295 ± 2K with a focus on the product formation. O2 concentrations in the carrier gas were in the range of (7.7–84) × 1014 molecule cm−3. The primary stable products detected were phenol, benzene oxide/oxepin and a not identified compound with the probable composition C5H6O. The yields of phenol and benzene oxide/oxepin were 0.12 ± 0.02 and 0.26 ± 0.06, respectively, being not affected by the experimental conditions. For benzene oxide/oxepin, a rapid consecutive reaction with O(3P) atoms was observed with a rate coefficient of k(295K) = (1.1 ± 0.1) × 10−10cm3 molecule−1s−1 measured at a pressure of 100mbar. A substance with the formula C6H6O2 (likely oxepin 4,5-epoxide or oxepin 2,3-epoxide), the isomers of muconaldehyde, as well as formic acid, acrolein and trans-butenedial were identified as products of the reaction of O(3P) atoms with benzene oxide/oxepin.

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