Radiation chemistry of carbon tetrafluoride-carbon tetrachloride mixtures in the gas phase

1972 ◽  
Vol 76 (25) ◽  
pp. 3734-3741 ◽  
Author(s):  
Ronald E. Marcotte ◽  
Robert J. Hanrahan
1953 ◽  
Vol 31 (4) ◽  
pp. 328-337 ◽  
Author(s):  
L. Breitman ◽  
E. W. R. Steacie

The infrared spectra of chloral, carbon tetrachloride, and chloroform have been determined between 1500 and 650 cm.−1 over a range of pressures in the gas phase. Absorption bands suitable for the quantitative analysis of binary and ternary mixtures of the components have been selected and their peak intensities shown to obey Beer's Law over the range of pressures studied. Ternary mixtures have been analyzed from the spectra with an accuracy of about 20%.The spectra of dichloromethane and methyl chloride have also been measured under comparable conditions.


1964 ◽  
Vol 42 (3) ◽  
pp. 669-681 ◽  
Author(s):  
J. A. Stone ◽  
P. J. Dyne

A study of the effect of the addition of small amounts (<3.5%) of the halogenated compounds CCl4, CHCl3, and CDCl3 on the radiolysis of cyclohexane has shown that processes other than radical scavenging occur. At the lowest concentrations of solute that it was practical to employ (0.004 M) cyclohexyl radicals were scavenged without a corresponding reduction in the hydrogen yield. At higher solute concentrations G(H2) was reduced by a physical process which did not involve the scavenging of thermal hydrogen atoms but did lead to chemical reaction involving the solute.


1975 ◽  
Vol 6 (12) ◽  
pp. no-no
Author(s):  
DOUGLAS D. DAVIS ◽  
JOHN F. SCHMIDT ◽  
CHARLES M. NEELEY ◽  
ROBERT J. HANRAHAN

1970 ◽  
Vol 44 (2) ◽  
pp. 296 ◽  
Author(s):  
James W. Buchanan ◽  
Robert J. Hanrahan

1976 ◽  
Vol 6 (4) ◽  
pp. 265-276 ◽  
Author(s):  
R.E. Rebbert ◽  
P.J. Ausloos

Sign in / Sign up

Export Citation Format

Share Document