Temperature and pressure dependence of the nonmetal-metal transition in sodium-ammonia solutions (electrical conductivity and pressure-volume-temperature data up to 150.deg. and 1000 bars

1975 ◽  
Vol 79 (26) ◽  
pp. 2922-2928 ◽  
Author(s):  
S. Hahne ◽  
U. Schindewolf
2015 ◽  
Vol 276 ◽  
pp. 136-141 ◽  
Author(s):  
Haiying Hu ◽  
Lidong Dai ◽  
Heping Li ◽  
Keshi Hui ◽  
Jia Li

1999 ◽  
Vol 52 (5) ◽  
pp. 373 ◽  
Author(s):  
Nashiour Rohman ◽  
Sekh Mahiuddin ◽  
Raymond Aich ◽  
Klaus Tödheide

Electrical conductivities of molten trimethylpentylammonium triethyloctylborate (N1115B2228) and triethylpentylammonium triethylpentylborate (N2225B2225) were measured as functions of temperature (c. 293 · 15–383 · 15 K) and pressure (from 1 bar to 5 kbar). Analysis of the temperature dependence of the electrical conductivity was made by using the Vogel–Tammann–Fulcher equation, κ = Aexp[ – B/(T – T0)]. The empirical nature of the pressure dependence of the B and T0 parameters has revealed the possibility of obtaining an isothermal equation to explain the pressure dependence of the electrical conductivity. Accordingly, an empirical equation of the form κ = a′exp(b′ P+c′ P2) has been found to describe the pressure dependence of the electrical conductivity. The ideal glass transition temperature, T0, is the key parameter in controlling the pressure dependence of the electrical conductivity for both systems under study.


2015 ◽  
Vol 60 (5) ◽  
pp. 1495-1503 ◽  
Author(s):  
Mitsuhiro Kanakubo ◽  
Kenneth R. Harris ◽  
Noriaki Tsuchihashi ◽  
Kazuyasu Ibuki ◽  
Masakatsu Ueno

Author(s):  
S Bair

A thorough characterization of all viscous flow properties relevant to steady simple shear was carried out for five liquid lubricants of current interest to tribology. Shear stresses were generated to values significant to concentrated contact lubrication. Two types of non-Newtonian response were observed: shear-thinning as a power-law fluid and near rate-independence. Functions and parameters were obtained for the temperature and pressure dependence of the viscosity and of the time constant for the Carreau-Yasuda equation. Results are consistent with free volume and kinetic theory, but directly contradict many assumptions currently utilized for numerical simulation and for extracting rheological properties from contact measurements.


2003 ◽  
Vol 81 (1-2) ◽  
pp. 47-53 ◽  
Author(s):  
M B Helgerud ◽  
W F Waite ◽  
S H Kirby ◽  
A Nur

We report on compressional- and shear-wave-speed measurements made on compacted polycrystalline sI methane and sII methane–ethane hydrate. The gas hydrate samples are synthesized directly in the measurement apparatus by warming granulated ice to 17°C in the presence of a clathrate-forming gas at high pressure (methane for sI, 90.2% methane, 9.8% ethane for sII). Porosity is eliminated after hydrate synthesis by compacting the sample in the synthesis pressure vessel between a hydraulic ram and a fixed end-plug, both containing shear-wave transducers. Wave-speed measurements are made between –20 and 15°C and 0 to 105 MPa applied piston pressure. PACS No.: 61.60Lj


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