Temperature and pressure dependence of the electrical conductivity of the ionic liquids 1-methyl-3-octylimidazolium hexafluorophosphate and 1-methyl-3-octylimidazolium tetrafluoroborate

2007 ◽  
Vol 261 (1-2) ◽  
pp. 414-420 ◽  
Author(s):  
Mitsuhiro Kanakubo ◽  
Kenneth R. Harris ◽  
Noriaki Tsuchihashi ◽  
Kazuyasu Ibuki ◽  
Masakatsu Ueno
Author(s):  
Florian Pabst ◽  
Zaneta Wojnarowska ◽  
Marian Paluch ◽  
Thomas Blochowicz

The temperature and pressure dependence of two dynamic processes in the dielectric spectra of five supercooled ionic liquids equipped with octyl-chains are reported. The microscopic origin of these processes is discussed.


2015 ◽  
Vol 276 ◽  
pp. 136-141 ◽  
Author(s):  
Haiying Hu ◽  
Lidong Dai ◽  
Heping Li ◽  
Keshi Hui ◽  
Jia Li

1999 ◽  
Vol 52 (5) ◽  
pp. 373 ◽  
Author(s):  
Nashiour Rohman ◽  
Sekh Mahiuddin ◽  
Raymond Aich ◽  
Klaus Tödheide

Electrical conductivities of molten trimethylpentylammonium triethyloctylborate (N1115B2228) and triethylpentylammonium triethylpentylborate (N2225B2225) were measured as functions of temperature (c. 293 · 15–383 · 15 K) and pressure (from 1 bar to 5 kbar). Analysis of the temperature dependence of the electrical conductivity was made by using the Vogel–Tammann–Fulcher equation, κ = Aexp[ – B/(T – T0)]. The empirical nature of the pressure dependence of the B and T0 parameters has revealed the possibility of obtaining an isothermal equation to explain the pressure dependence of the electrical conductivity. Accordingly, an empirical equation of the form κ = a′exp(b′ P+c′ P2) has been found to describe the pressure dependence of the electrical conductivity. The ideal glass transition temperature, T0, is the key parameter in controlling the pressure dependence of the electrical conductivity for both systems under study.


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