Physicochemical properties of aqueous mixtures of tetrabutylammonium bromide and anionic surfactants. 1. Temperature-induced micellar growth and cloud point phenomenon

1989 ◽  
Vol 93 (21) ◽  
pp. 7441-7445 ◽  
Author(s):  
Zhi Jian Yu ◽  
Guangzhi Xu
Keyword(s):  
Physicochemical Properties ◽  
Cloud Point ◽  
Anionic Surfactants ◽  
Tetrabutylammonium Bromide ◽  
Aqueous Mixtures ◽  
Micellar Growth

Spontaneous Vesicles and other Solution Structures in Catanionic Mixtures

1991 ◽  
Vol 248 ◽  
Author(s):  
Eric W. Kaler ◽  
Kathleen L. Herrington ◽  
Joseph A. N. Zasadzinski
Keyword(s):  
Anionic Surfactants ◽  
Structural Studies ◽  
Aqueous Mixtures ◽  
Approach To Equilibrium ◽  
Equilibrium Form ◽  
Solution Structures ◽  
Catanionic Vesicles ◽  
Cationic And Anionic Surfactants ◽  
Physical And Chemical ◽  
Catanionic Mixtures

AbstractWe have prepared spontaneous, single-walled, equilibrium vesicles of controlled size and surface charge from aqueous mixtures of simple, commercially available, single-tailed cationic and anionic surfactants. We believe vesicle formation results from the production of anion-cation surfactant pairs which then act as double-tailed zwitterionic surfactants. Although unilamellar vesicles have been created by numerous physical and chemical techniques from multilamellar dispersions, all such vesicle systems revert to the equilibrium, multilamellar phase over time. These catanionic vesicles are stable for periods as long as several years and appear to be the equilibrium form of aggregation. Here we review the phase behavior and structural studies of several such mixtures, with particular focus on the effect of surfactant tail lengths on size and location of the vesicle phase in the appropriate phase diagram. The approach to equilibrium is also discussed.

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