Chemiluminescent reactions of ozone with dimethyl sulfoxide and dimethyl disulfide. Formation of electronically excited sulfur dioxide

1985 ◽  
Vol 89 (1) ◽  
pp. 33-38 ◽  
Author(s):  
Robert J. Glinski ◽  
David A. Dixon
1968 ◽  
Vol 72 (11) ◽  
pp. 3711-3714 ◽  
Author(s):  
B. A. Thrush ◽  
Christopher J. Halstead ◽  
A. McKenzie

1983 ◽  
Vol 36 (10) ◽  
pp. 1991 ◽  
Author(s):  
NK Graham ◽  
JB Gill ◽  
DC Goodall

The metals Ti, Zr, V, Cr, Mo, Fe, Ni and Sn dissolve electrolytically in the binary solvent system dimethyl sulfoxide-sulfur dioxide, forming metal disulfates; W forms sulfate. The metals dissolve electrolytically in other binary systems containing sulfur dioxide, forming mixtures of sulfur oxyanions. The importance of solvent parameters in metal reactivity is discussed, together with the mechanism of the reactions.


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