Absolute rate constants for the gas-phase reactions of the nitrogen trioxide radical with methanethiol, dimethyl sulfide, dimethyl disulfide, hydrogen sulfide, sulfur dioxide, and dimethyl ether over the temperature range 280-350 K

1986 ◽  
Vol 90 (21) ◽  
pp. 5393-5396 ◽  
Author(s):  
Timothy J. Wallington ◽  
Roger Atkinson ◽  
Arthur M. Winer ◽  
James N. Pitts
Keyword(s):  
Hydrogen Sulfide ◽  
Sulfur Dioxide ◽  
Gas Phase ◽  
Dimethyl Ether ◽  
Rate Constants ◽  
Dimethyl Sulfide ◽  
Dimethyl Disulfide ◽  
Absolute Rate ◽  
Sulfide Sulfur ◽  
Gas Phase Reactions

The reactions of O(3P) with the butanols

1983 ◽  
Vol 61 (12) ◽  
pp. 2716-2720 ◽  
Author(s):  
John M. Roscoe
Keyword(s):  
Free Energy ◽  
Gas Phase ◽  
Rate Constants ◽  
Substrate Concentration ◽  
Kinetic Data ◽  
Absolute Rate ◽  
Gas Phase Reactions ◽  
Linear Free Energy ◽  
Different Types ◽  
Energy Relations

The reactions of O(3P) with the butanols were studied kinetically as a function of temperature and substrate concentration. The absolute rate constants for the gas phase reactions, in the units M−1 s−1, obey the following relations.[Formula: see text]The results suggest that although the α-CH bond in these alcohols is the most reactive one, reaction of O(3P) with other CH bonds in the alcohols is also appreciable. The kinetic data for these and other alcohols are separated into contributions from the different types of CH bonds and the results are discussed in terms of linear free energy relations.

Absolute rate constants for the gas-phase reactions of silylene with silane, disilane and the methylsilanes

1990 ◽  
Vol 86 (1) ◽  
pp. 27 ◽  
Author(s):  
James E. Baggott ◽  
H. Monty Frey ◽  
Phillip D. Lightfoot ◽  
Robin Walsh ◽  
Ivy M. Watts
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Absolute Rate ◽  
Gas Phase Reactions
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