Preparation of Robust, Thin Zeolite Membrane Sheet for Molecular Separation

2011 ◽  
Vol 50 (20) ◽  
pp. 11677-11689 ◽  
Author(s):  
Wei Liu ◽  
Jian Zhang ◽  
Nathan Canfield ◽  
L. Saraf
Keyword(s):  
Zeolite Membrane ◽  
Molecular Separation ◽  
Membrane Sheet

Iono-molecular Separation with Composite Membranes II. Preparation and characterization of polysulphone and composite nanoparticles

2017 ◽  
Vol 68 (2) ◽  
pp. 203-209
Author(s):  
Hussam Nadum Abdalraheem Al Ani ◽  
Anca Maria Cimbru ◽  
Corneliu Trisca-Rusu ◽  
Szidonia Katalin Tanczos ◽  
Adriana Cuciureanu ◽  
...  
Keyword(s):  
Chemical Species ◽  
Composite Membranes ◽  
Ammonium Persulfate ◽  
Operating Pressure ◽  
Polysulfone Membrane ◽  
Polymeric Nanoparticle ◽  
Molecular Separation ◽  
Copper Complexation ◽  
Molecular Separations ◽  
Methyl Pyrrolidone

This paper illustrates the possibility of producing iono-molecular separations using ionic colloidal ultrafiltration membrane of polysulfone synthetic solutions of cupric ions and nitro phenols through ultrafiltration assisted by polymeric nanoparticle composites based on polysulfone. In the present work, in order to reduce the operating pressure and increase the flow of water we are using the process of ultrafiltration through a polysulfone membrane in N-methylpyrrolidone 10% prepared by coagulation in isopropanol. The nanoparticles needed in colloidal ultrafiltration had been obtained through the immersion technique of precipitation of a solution of 5% PSf in N-methyl pyrrolidone containing 3% aniline in lower alcohols: methanol, ethanol, and isopropanol, followed by the oxidation of the remaining aniline in a solution of 10% hydrochloric acid and ammonium persulfate. The Nanoparticles of polysulfone (NP-PSf) and The three obtained variants of nanoparticles composites (NP-PSf-PANI) were morphologically (SEM) and (AFM), structurally and compositionally (FTIR) characterized and the results show that nanoparticles polysulfone have a much lower range than the composites. The Possibility of copper complexation by both nitrophenols, and by nanoparticle surface probably lead to the formation of more stable aggregates in the supply, which can sufficiently justify the increased retention. The Retentions of the chemical species in question use in all the tests made the same series:R NP-PSf-PANI-M] R NP-PSf-PANI-E] R NP-PSf-PANI-P] R NP-PSf

Iono-molecular Separation with Composite Membranes VI. Nitro-phenol separation through sulfonated polyether ether ketone on capillary polypropylene membranes

2018 ◽  
Vol 69 (7) ◽  
pp. 1603-1607
Author(s):  
Ion Spiridon Din ◽  
Anca Maria Cimbru ◽  
Abbas Abdul Kadhim Klaif Rikabi ◽  
Szidonia Katalin Tanczos ◽  
Simona Ticu (Cotorcea) ◽  
...  
Keyword(s):  
Flow Rate ◽  
Water Solubility ◽  
Composite Membranes ◽  
Membrane System ◽  
Polyether Ether Ketone ◽  
Molecular Separation ◽  
Capillary Membrane ◽  
Sulfonated Polyether Ether Ketone ◽  
Source Phase ◽  
Receptor Phase

The importance of removing and / or separating nitro phenols from aqueous solutions through membranes is substantiated by the multitude of recent research in the field, which broadly justifies both the economic and ecological reasons of such an approach. The present paper outlines the results of the transfer of nitro phenols through a membrane system made up of PPET impregnated polypropylene capillaries (PP) impregnated with sulfonate polyetheretherketone (SPEEK). The experiments were carried out in a PP-SPEEK capillary membrane module, with a useful size of 1 m2. Determinations made by using a 4 L / min flow rate source at a 5 mg / l nitrophenol concentration and pH 5 or pH 7, and the pH 12 receiving phase and a flow rate of 0.3 L / min, revealed that o- and p-nitrophenol were transferred much faster than m-nitrophenol (the flux is nearly double); the source phase of the system is concentrated in m-nitrophenol, and the receptor phase in o- and p-nitro phenols; the transfer data correlates with the higher water solubility of m-nitrophenol; mono nitro phenols transfer much faster than di nitrophenol, but both the mono and di nitrophenol streams decrease over time; after 4-5 hours of work, the mono nitrophenol concentration triples in the receiving phase, while the 2,4-dinitrophenol concentration doubles in the source phase.

scholarly journals Gas Permeation Properties of High-Silica CHA-Type Zeolite Membrane

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 249
Author(s):  
Yasuhisa Hasegawa ◽  
Chie Abe ◽  
Mayumi Natsui ◽  
Ayumi Ikeda
Keyword(s):  
Molecular Size ◽  
Gas Permeation ◽  
Zeolite Membrane ◽  
Type Zeolite ◽  
High Silica ◽  
Separation Of Co2 ◽  
Α Al2o3 ◽  
Separation Performances ◽  
Molecular Sieving ◽  
Permeation Properties

The polycrystalline CHA-type zeolite layer with Si/Al = 18 was formed on the porous α-Al2O3 tube in this study, and the gas permeation properties were determined using single-component H2, CO2, N2, CH4, n-C4H10, and SF6 at 303–473 K. The membrane showed permeation behavior, wherein the permeance reduced with the molecular size, attributed to the effect of molecular sieving. The separation performances were also determined using the equimolar mixtures of N2–SF6, CO2–N2, and CO2–CH4. As a result, the N2/SF6 and CO2/CH4 selectivities were as high as 710 and 240, respectively. However, the CO2/N2 selectivity was only 25. These results propose that the high-silica CHA-type zeolite membrane is suitable for the separation of CO2 from CH4 by the effect of molecular sieving.

Large-Area Ti3C2Tx-MXene Coating: Toward Industrial-Scale Fabrication and Molecular Separation

ACS Nano ◽  
2021 ◽  
Author(s):  
Ji Hoon Kim ◽  
Gyeong Seok Park ◽  
Yong-Jae Kim ◽  
Eunji Choi ◽  
Junhyeok Kang ◽  
...  
Keyword(s):  
Industrial Scale ◽  
Large Area ◽  
Molecular Separation

scholarly journals Hexane isomers separation on an isoreticular series of microporous Zr carboxylate metal organic frameworks

2020 ◽  
Vol 8 (34) ◽  
pp. 17780-17789
Author(s):  
Adriano Henrique ◽  
Tanmoy Maity ◽  
Hengli Zhao ◽  
Pedro F. Brântuas ◽  
Alírio E. Rodrigues ◽  
...  
Keyword(s):  
High Selectivity ◽  
Metal Organic Frameworks ◽  
Degree Of Branching ◽  
Molecular Separation ◽  
Metal Organic ◽  
Gcmc Simulations

The microporous MOF MIL-140B can separate hexane isomers according to the degree of branching, linear >mono-branched >di-branched, with a remarkably high selectivity up to 10 at 343 K. GCMC simulations confirm the origins of the molecular separation.

Two-dimensional graphene oxide based membranes for ionic and molecular separation: Current status and challenges

2021 ◽  
pp. 105605
Author(s):  
Shania Sharif ◽  
Khuram Shahzad Ahmad ◽  
Faisal Rehman ◽  
Zubeda Bhatti ◽  
Khalid Hussain Thebo
Keyword(s):  
Graphene Oxide ◽  
Current Status ◽  
Two Dimensional ◽  
Molecular Separation

scholarly journals Water friction in nanofluidic channels made from two-dimensional crystals

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Ashok Keerthi ◽  
Solleti Goutham ◽  
Yi You ◽  
Pawin Iamprasertkun ◽  
Robert A. W. Dryfe ◽  
...  
Keyword(s):  
Hexagonal Boron Nitride ◽  
Slip Length ◽  
Two Dimensional ◽  
Water Flows ◽  
Nanofluidic Channels ◽  
Molecular Separation ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Biological Channels ◽  
Atomically Flat

AbstractMembrane-based applications such as osmotic power generation, desalination and molecular separation would benefit from decreasing water friction in nanoscale channels. However, mechanisms that allow fast water flows are not fully understood yet. Here we report angstrom-scale capillaries made from atomically flat crystals and study the effect of confining walls’ material on water friction. A massive difference is observed between channels made from isostructural graphite and hexagonal boron nitride, which is attributed to different electrostatic and chemical interactions at the solid-liquid interface. Using precision microgravimetry and ion streaming measurements, we evaluate the slip length, a measure of water friction, and investigate its possible links with electrical conductivity, wettability, surface charge and polarity of the confining walls. We also show that water friction can be controlled using hybrid capillaries with different slip lengths at opposing walls. The reported advances extend nanofluidics’ toolkit for designing smart membranes and mimicking manifold machinery of biological channels.

Zeolite membrane reactors: from preparation to application in heterogeneous catalytic reactions

2021 ◽  
Author(s):  
I. G. Wenten ◽  
K. Khoiruddin ◽  
R. R. Mukti ◽  
W. Rahmah ◽  
Z. Wang ◽  
...  
Keyword(s):  
Chemical Reaction ◽  
Membrane Reactor ◽  
Membrane Separation ◽  
Process Intensification ◽  
Catalytic Reactions ◽  
Membrane Reactors ◽  
Zeolite Membrane ◽  
Heterogeneous Catalytic

Coupling chemical reaction with membrane separation or known as membrane reactor (MR) has been demonstrated by numerous studies and showed that this strategy has successfully addressed the goal of process intensification.

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