Coordination Polymers:  Structural Transformation from Two to Three Dimensions through Ligand Conformation Change

2000 ◽  
Vol 39 (9) ◽  
pp. 1990-1993 ◽  
Author(s):  
Zhan Shi ◽  
Lirong Zhang ◽  
Shan Gao ◽  
Guoyu Yang ◽  
Jia Hua ◽  
...  
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Three Dimensions ◽  
Conformation Change ◽  
Ligand Conformation

scholarly journals One-Dimensional Mercury Halide Coordination Polymers Based on A Semi-Rigid N-Donor Ligand: Reversible Structural Transformation

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 436 ◽  
Author(s):  
Pradhumna Mahat Chhetri ◽  
Xiang-Kai Yang ◽  
Chih-Tung Yang ◽  
Jhy-Der Chen
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Pyridyl Ring ◽  
Donor Ligand ◽  
One Dimensional ◽  
Ring Rotation ◽  
Mercury Halide ◽  
Ligand Conformation ◽  
Reversible Structural Transformation

Four one-dimensional (1D) mercury(II) halide coordination polymers have been synthesized by using a semi-rigid N-donor ligand, 2,2′-(1,4-phenylene)-bis(N-(pyridin-3-yl)acetamide) (1,4-pbpa). While [Hg(1,4-pbpa)Cl2·CH3OH]n, 1, forms a sinusoidal chain, the complexes [Hg(1,4-pbpa)X2]n (X = Cl, 2; Br, 3; I, 4) are helical. The sinusoidal 1 undergoes reversible structural transformation with helical 2 upon removal and uptake of CH3OH, which was accompanied with the conformation adjustment of the 1,4-pbpa ligand from trans anti-anti to trans syn-anti. Pyridyl ring rotation of the 1,4-pbpa ligand that results in the change of the ligand conformation is proposed for the initiation of the structural transformation.

Humidity-Induced Structural Transformation in Pseudopolymorph Coordination Polymers

2021 ◽  
Author(s):  
Behrouz Notash ◽  
Mona Farhadi Rodbari ◽  
Gianpiero Gallo ◽  
Robert Dinnebier
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers

scholarly journals Hydrated metal(II) complexes of N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl) derivatives of glycine, glycylglycine, threonine, serine, valine and methionine: a monomeric complex and coordination polymers in one, two and three dimensions linked by hydrogen bonding. Corrigendum

2006 ◽  
Vol 62 (1) ◽  
pp. 165-165
Author(s):  
M. Luz Godino Salido ◽  
Paloma Arranz Mascarós ◽  
Rafaél López Garzón ◽  
M. Dolores Gutiérrez Valero ◽  
John N. Low ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Synchrotron Radiation ◽  
Data Collection ◽  
Coordination Polymers ◽  
Data Reduction ◽  
Three Dimensions ◽  
Compound Viii ◽  
Monomeric Complex ◽  
Cell Refinement ◽  
Derivatives Of

Some of the data collection details for compound (VIII) were incorrectly given in Table 1 of Godino Salido et al. (2004). The data for compound VIII in this paper were collected using synchrotron radiation at the Daresbury SRS station 9.8, λ = 0.6935 Å (Cernik et al., 1997; Clegg, 2000). The data were collected using a Bruker SMART 1K CCD diffractometer using ω rotation with narrow frames. The computer program used in the data collection was SMART (Bruker, 2001) and for cell refinement and data reduction SAINT (Bruker, 2001).

Recent advances in structures and applications of coordination polymers based on cyclohexanepolycarboxylate ligands

2022 ◽  
Author(s):  
Yong-Cong Ou ◽  
Ri-Ming Zhong ◽  
Jian-Zhong Wu
Keyword(s):  
Coordination Polymers ◽  
Organic Ligands ◽  
Three Dimensions ◽  
Crystalline Materials ◽  
Recent Advances ◽  
Coordination Bonds

Coordination polymers (CPs) are emerging crystalline materials constructed by metal entities and organic ligands through coordination bonds, containing infinite coordination units in one, two, or three dimensions. Here an overview...

Structural diversity and modification in Ni(ii) coordination polymers: a peculiar phenomenon of reversible structural transformation between a 1D ladder and 2D layer

CrystEngComm ◽  
2020 ◽  
Vol 22 (44) ◽  
pp. 7565-7574
Author(s):  
Chia-Jou Chen ◽  
Wei-Te Lee ◽  
Ji-Hong Hu ◽  
Pradhumna Mahat Chhetri ◽  
Jhy-Der Chen
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Structural Diversity ◽  
Reversible Structural Transformation ◽  
Peculiar Phenomenon

The coordination of 5-tert-IPA2− ligands, the relaxation of the interdigitated 2D net and the breaking and connecting of the bis-pyridyl-bis-amide ligand demonstrate the peculiar reversible structural transformation between a 1D ladder and 2D layer.

Assembly of 1D, 2D and 3D lanthanum(iii) coordination polymers with perchlorinated benzenedicarboxylates: positional isomeric effect, structural transformation and ring-opening polymerisation of glycolide

2016 ◽  
Vol 45 (8) ◽  
pp. 3577-3589 ◽  
Author(s):  
Sheng-Chun Chen ◽  
An-Qi Dai ◽  
Kun-Lin Huang ◽  
Zhi-Hui Zhang ◽  
Ai-Jun Cui ◽  
...  
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Ring Opening ◽  
Catalytic Activities ◽  
Isomeric Effect ◽  
2D And 3D

Eight La(iii) coordination polymers were prepared from isomeric perchlorinated benzenedicarboxylate ligands, and their catalytic activities have been described.

Syntheses, structures, and magnetic properties of two unique Cu(ii)-based coordination polymers involving a crystal-to-crystal structural transformation from a 1D chain to a 3D network

2017 ◽  
Vol 46 (48) ◽  
pp. 17025-17031 ◽  
Author(s):  
Xu-Feng Yang ◽  
Min Liu ◽  
Hai-Bin Zhu ◽  
Cheng Hang ◽  
Yue Zhao
Keyword(s):  
Magnetic Properties ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Network Structure ◽  
Chain Structure ◽  
3D Network ◽  
1D Chain ◽  
Crystal Structural

Promoted by the DMF solvent, the 1D chain structure of 1 can be irreversibly transformed into the 3D sod network structure of 2 in a crystal-to-crystal fashion, which is accompanied by a drastic magnetic change.

Two- and three-dimensional Zn(ii) coordination polymers constructed from mixed ligand systems: interpenetration, structural transformation and sensing behavior

CrystEngComm ◽  
2016 ◽  
Vol 18 (23) ◽  
pp. 4349-4358 ◽  
Author(s):  
Min Kyung Park ◽  
Kwang Soo Lim ◽  
Ji Hey Park ◽  
Jeong Hwa Song ◽  
Dong Won Kang ◽  
...  
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Mixed Ligand

Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic properties of 1D azido-Cu(ii) chains with a carboxylate bridge

2019 ◽  
Vol 48 (30) ◽  
pp. 11268-11277 ◽  
Author(s):  
Xiangyu Liu ◽  
Xiufang Ma ◽  
Jinhui Yang ◽  
Shuchang Luo ◽  
Zheng Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Solvent Effect ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Crystal Transformation ◽  
Carboxylate Bridge ◽  
Copper Coordination

The solvent effect leads to structural transformation and tunable magnetism of chain-like azido-copper coordination polymers.

Tetrathiopyridyl-tetrathiafulvalene-based Cd(ii) coordination polymers: one ligand, one metal cation, many possibilities

2019 ◽  
Vol 43 (36) ◽  
pp. 14291-14298 ◽  
Author(s):  
Damien Bechu ◽  
Guillaume Rogez ◽  
Mir Wais Hosseini ◽  
Stéphane A. Baudron
Keyword(s):  
Coordination Polymers ◽  
Metal Cation ◽  
Structural Organization ◽  
Ligand Conformation ◽  
Tetrathiafulvalene Derivative

A novel tetrathiafulvalene derivative bearing four 4-thiopyridyl units has been assembled with Cd(ii) salts for the construction of a series of coordination polymers with different structural organization depending on the ligand conformation.

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